SYNTHESES AND CRYSTAL STRUCTURE ANALYSES OF PENTACARBONYL TUNGSTEN COMPLEXES WITH TETRA-TERT.-BUTYLCYCLOTETRASTIBANE AND TETRAPHENYLDISTIBANE LIGANDS German

Breunig HJ.; Pawlik J.

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SYNTHESES AND CRYSTAL STRUCTURE ANALYSES OF PENTACARBONYL TUNGSTEN COMPLEXES WITH TETRA-TERT.-BUTYLCYCLOTETRASTIBANE AND TETRAPHENYLDISTIBANE LIGANDS German

机译：五羰基钨与四叔丁基环四磷锗和四苯基二锡烷配体的合成和晶体结构分析德语

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The synthesis of (tBuSb)(4)W(CO)(5)(2) (1) is performed by reaction of (tBuSb)(4) with W(CO)(5)THF in a 1:2 molar ratio. The reaction in the 1:1 ratio gives (tBuSb)(4)W(CO)(5) (2). The crystal structures of 1 and (Ph(4)Sb(2))W(CO)(5)(2) (3) are reported. References: 13

机译：（tBuSb）（4）[W（CO）（5）]（2）（1）的合成是通过（tBuSb）（4）与 W（CO）（5）THF 以 1：2 的摩尔比反应进行的。以 1：1 的比例反应得到（tBuSb）（4）W（CO）（5）（2）。报道了1和（Ph（4）Sb（2））[W（CO）（5）]（2）（3）的晶体结构。[参考文献： 13]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第5期|817-822|共6页
作者
Breunig HJ.; Pawlik J.;
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作者单位

UNIV BREMEN INST ANORGAN & PHYS CHEM LEOBENER STR D-28359 BREMEN GERMANY;

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正文语种德语
中图分类化学;
关键词
Pentacarbonyl(tetra-tert; -butyl-cyclotetrastibane)-tungsten complexes; Mu-tetra-phenyldistibanebis(pentacarbonyl-tungsten); X-ray structure analyses; Hexacarbonyl;

机译：五羰基（四叔;-丁基-环四磷锹）-钨络合物;Mu-tetra-phenyldistibanebis（pentacarbonyl-tungsten）;X射线结构分析;六羰基;

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机译：Supramolecular architectures of mononuclear nickel(II) and homobinuclear copper(II) complexes with the 5,5 '-dimethyl-2,2 '-bipyridine ligand: Syntheses, crystal structures and Hirshfeld surface analyses
2. ChemInform Abstract: Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 104. Trimetal Molybdenum and Tungsten Complexes Containing η5‐C2B9H9R′2 (R′: H or Me) Ligands; Crystal Structure of (NEt4)(Mo2W(μ3‐CC6H4Me‐4)(μ‐CO)(CO)7(PMe3)(η5‐C2B9H9Me2)). [J] . S. J. DOSSETT, I. J. HART, M. U. PILOTTIF. G. A. STONE Chem Inform . 1991,第6期

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SYNTHESES AND CRYSTAL STRUCTURE ANALYSES OF PENTACARBONYL TUNGSTEN COMPLEXES WITH TETRA-TERT.-BUTYLCYCLOTETRASTIBANE AND TETRAPHENYLDISTIBANE LIGANDS German

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