CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .237. ON THE REACTION OF DIPHOSPHANE(4) WITH PEROXO COMPOUNDS - FORMATION OF PHOSPHINOPHOSPHINIC ACID, H2PPH(O)OH, AND BIS(PHOSPHINO)PHOSPHINIC ACID, (H2P)(2)P(O)OH German

Baudler M.; Heumuller H.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .237. ON THE REACTION OF DIPHOSPHANE(4) WITH PEROXO COMPOUNDS - FORMATION OF PHOSPHINOPHOSPHINIC ACID, H2PPH(O)OH, AND BIS(PHOSPHINO)PHOSPHINIC ACID, (H2P)(2)P(O)OH German

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CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .237. ON THE REACTION OF DIPHOSPHANE(4) WITH PEROXO COMPOUNDS - FORMATION OF PHOSPHINOPHOSPHINIC ACID, H2PPH(O)OH, AND BIS(PHOSPHINO)PHOSPHINIC ACID, (H2P)(2)P(O)OH German

机译：对磷化学的贡献 .237.关于二磷烷（4）与过氧化物的反应 - 膦膦酸 H2PPH（O）OH 和双（膦）次膦酸的形成，（H2P）（2）P（O）OH 德语

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Diphosphane(4) reacts with peroxo compounds such as hydrogen peroxide, tetraline hydroperoxide, trifluoroperoxyacetic acid, and cumene hydroperoxide (which is particularly suited for preparative work) at -30 degrees C to furnish phosphinophosphinic acid, H2PPH(O)OH (1), as the primary product. Compound 1 disproportionates to a major extent in statu nascendi to give phosphanes (above all PH3) and monophosphorus acids of various oxidation states as well as some bis(phosphino)phosphinic acid, (H2P)(2)P(O)OH (2). The acids 1 and 2 can be trapped and stabilized as their triethylammonium salts. The structures of these salts have been determined by spectroscopic investigations. References: 20

机译：二膦烷（4）与过氧化氢、四氢过氧化氢、三氟过氧乙酸和过氧化氢异丙苯（特别适合制备工作）等过氧化氢化合物在-30°C下反应，生成亚膦酸H2PPH（O）OH（1）作为主要产物。化合物 1 在 statu nascendi 中在很大程度上不成比例地产生各种氧化态的磷酸盐（尤其是 PH3）和单磷酸以及一些双（膦）膦酸（H2P）（2）P（O）OH （2）。酸 1 和 2 可以作为其三乙基铵盐被捕获和稳定。这些盐的结构是通过光谱研究确定的。[参考文献： 20]

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第10期|1689-1692|共4页
作者
Baudler M.; Heumuller H.;
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作者单位

UNIV COLOGNE INST ANORGAN CHEM GREINSTR 6 D-50939 COLOGNE GERMANY;

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正文语种德语
中图分类化学;
关键词
Diphosphane(4); Phosphinophosphinic acid; Bis(phosphino)phosphinic acid; Cumene hydroperoxide;

机译：二膦（4）;膦基膦酸;双（膦）次膦酸;过氧化氢异丙苯;

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1. ChemInform Abstract: Chemistry of Phosphorus. Part 237. Reaction of Diphosphane(4) with Peroxo Compounds: Formation of Phosphinophosphinic Acid, H2PPH(O)OH, and Bis(phosphino)phosphinic Acid, (H2P)2P(O)OH. [J] . M. BAUDLER, H. HEUMUELLER Chem Inform . 1996,第2期

机译：ChemInform Abstract: Chemistry of Phosphorus. Part 237. Reaction of Diphosphane(4) with Peroxo Compounds: Formation of Phosphinophosphinic Acid, H2PPH(O)OH, and Bis(phosphino)phosphinic Acid, (H2P)2P(O)OH.
2. ChemInform Abstract: Organic Phosphorus Compounds. Part 101. Preparation and Physical Properties of Bis(aminoalkyl)phosphinic Acids. [J] . L. MAIER Chem Inform . 1992,第25期

机译：ChemInform Abstract: Organic Phosphorus Compounds. Part 101. Preparation and Physical Properties of Bis(aminoalkyl)phosphinic Acids.
3. Organic phosphorus compounds 53 preparation and properties of bis‐(chloromethyl)‐phosphinic and ‐thiophosphinic acid derivatives as well as tertiary phosphine oxides and sulfides containing two ClCH2groups 1 [J] . Ludwig Maier helvetica chimica acta . 1971,第6期

机译：Organic phosphorus compounds 53 preparation and properties of bis‐(chloromethyl)‐phosphinic and ‐thiophosphinic acid derivatives as well as tertiary phosphine oxides and sulfides containing two ClCH2groups 1

CONTRIBUTIONS TO THE CHEMISTRY OF PHOSPHORUS .237. ON THE REACTION OF DIPHOSPHANE(4) WITH PEROXO COMPOUNDS - FORMATION OF PHOSPHINOPHOSPHINIC ACID, H2PPH(O)OH, AND BIS(PHOSPHINO)PHOSPHINIC ACID, (H2P)(2)P(O)OH German

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