CRYSTAL STRUCTURE OF BISLITHIUM-TRIS(TRIMETHYLSILYL)HYDRAZIDE AND REACTIONS WITH FLUOROBORANES, -SILANES, AND -PHOSPANES German

Bode K.; Noltemeyer M.; Witteabel H.Klingebiel U.

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CRYSTAL STRUCTURE OF BISLITHIUM-TRIS(TRIMETHYLSILYL)HYDRAZIDE AND REACTIONS WITH FLUOROBORANES, -SILANES, AND -PHOSPANES German

机译：双锂-三（三甲基硅基）酰肼的晶体结构以及与氟硼烷、-硅烷和-磷蜂的反应德语

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Tris(trimethylsilyl)hydrazine reacts with n-butyllithium in n-hexane to give the lithium-derivative 1. The reaction of 1 with SiF6, PhSiF(3), BF3 . OEt(2), F2BN(SiMe(3))(2) and PF3 leads to the substitution products 2-6. The 1,2-diaza-3-bora-5-silacyclopentane 7 is formed by heating (Me(3)si)(2)N-N(siMe(3))BFNSiMe(3))(2) (5) at 250 degrees C. In the reaction of (Me(3)Si)(2)N-N(SiMe(3))PF2 (6) with lithiated tert-butyl(trimethylsilyl)amine the hydrazino-iminophosphene (Me(3)Si)(2)N-N = P-N(SiMe(3))(CMe(3)) (8) is obtained. In the molar ratio 2:1 1 reacts with SiF4 and BF3 . OEt(2) to give bistris(trimethylsilyl)hydrazinosilane 9 and -borane 10. References: 13

机译：三（三甲基硅基）肼与正己烷中的正丁基锂反应，得到锂衍生物1。1 与 SiF6、PhSiF（3）、BF的反应3 .OEt（2）、F2BN（SiMe（3））（2）和PF3导致取代产物2-6。1,2-二氮杂-3-硼-5-硅环戊烷 7 是通过在 250 摄氏度下加热（Me（3）si）（2）N-N（siMe（3））BFNSiMe（3））（2）（5）形成的。在（Me（3）Si）（2）N-N（SiMe（3））PF2 （6）与锂化叔丁基（三甲基硅基）胺的反应中，得到肼基亚氨基膦（Me（3）Si）（2）N-N = P-N（SiMe（3））（CMe（3））（8）。摩尔比为 2：1 1 与 SiF4 和 BF3 反应。OEt（2）得到双[三（三甲基硅基）肼基]硅烷 9 和-硼烷 10。[参考文献： 13]

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第3期|500-505|共6页
作者
Bode K.; Noltemeyer M.; Witteabel H.Klingebiel U.;
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UNIV GOTTINGEN INST ANORGAN CHEM TAMMANNSTR 4 D-37077 GOTTINGEN GERMANY;

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正文语种德语
中图分类化学;
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Crystal structure; Bis(hydrazino)silane and -borane; Hydrazino-iminophosphene; 1; 2-diaza-3-bora-5-sila-cyclopentane; Iminoboranes;

机译：晶体结构;双（肼基）硅烷和硼烷;肼基亚氨基膦;1;2-二氮杂-3-硼-5-硅环戊烷;亚氨基硼烷类;

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1. ChemInform Abstract: Reactions of Silenes Produced Thermally from Pivaloyl‐ and Adamantoyltris(trimethylsilyl)silane with Bis(trimethylsilyl)butadiyne. [J] . Akinobu Naka, Mitsuo Ishikawa Chem Inform . 2002,第33期

机译：ChemInform Abstract: Reactions of Silenes Produced Thermally from Pivaloyl‐ and Adamantoyltris(trimethylsilyl)silane with Bis(trimethylsilyl)butadiyne.
2. ChemInform Abstract: Synthesis and Reactions of 2‐N,N‐Bis(trimethylsilyl)aminobenzonitrile ‐ Crystal Structure of NC(C6H4)N=MoCl3×3 MeCN and (( Me3Si)2N(C6H4)CN)2TiCl4. [J] . H. W. ROESKY, B. MELLER‐REHBEIN, M. NOLTEMEYER Chem Inform . 1991,第46期

机译：ChemInform Abstract: Synthesis and Reactions of 2‐N,N‐Bis(trimethylsilyl)aminobenzonitrile ‐ Crystal Structure of NC(C6H4)N=MoCl3×3 MeCN and (( Me3Si)2N(C6H4)CN)2TiCl4.
3. ChemInform Abstract: Palladium‐Mediated Reactions of Chloroformates with Phenylselenotris(trimethylsilyl)silane and Aryltellurotris(trimethylsilyl)silane: Improved Procedure for the Preparation of (Phenylseleno)‐ and (Aryltelluro)formates. [J] . C. H. SCHIESSER, M. A. SKIDMORE Chem Inform . 1998,第52期

机译：ChemInform Abstract: Palladium‐Mediated Reactions of Chloroformates with Phenylselenotris(trimethylsilyl)silane and Aryltellurotris(trimethylsilyl)silane: Improved Procedure for the Preparation of (Phenylseleno)‐ and (Aryltelluro)formates.

CRYSTAL STRUCTURE OF BISLITHIUM-TRIS(TRIMETHYLSILYL)HYDRAZIDE AND REACTIONS WITH FLUOROBORANES, -SILANES, AND -PHOSPANES German

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