Crystal structure and two-photon absorption properties study of a new zinc complex constructed by DMIT ligand

Hu Yali; Li Tingbin

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Crystal structure and two-photon absorption properties study of a new zinc complex constructed by DMIT ligand

机译：Crystal structure and two-photon absorption properties study of a new zinc complex constructed by DMIT ligand

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摘要

A new zinc complex bis(benzyltriethylammonium) bis(1,3-dithiole-2-thione-4,5-dithiolato)-zinc(II) has been synthesized, its crystal structure has been determined by means of X-ray single crystal diffraction. The central zinc(II) ion coordinates with two ligands which constructed a distorted tetrahedron environment, cation groups and ligands link each other through weak intermolecular C-H center dot center dot center dot S hydrogen bonds. Its two-photon absorption properties has been studied using open aperture Z-scan technique with 14 ps pulses at wavelength 532 nm, its two-photon absorption cross section sigma(2) value was determined to be 8.73 x 10(-53) (m(4).s/photon.molecule). The theoretical mechanism of the two-photon absorption process was analysized by simplied five-energy-band model. (C) 2014 Elsevier B.V. All rights reserved.

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来源
《Materials Chemistry and Physics》 |2014年第2期|75-78|共4页
作者
Hu Yali; Li Tingbin;
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作者单位

Taishan Univ, Dept Chem, Tai An 271021, Shandong, Peoples R China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类工程基础科学;工程材料学;
关键词
Optical materials; Chemical synthesis; Crystal structure; Optical properties; NONLINEAR-OPTICAL PROPERTY; 1; 3-DITHIOLE-2-THIONE-4; 5-DITHIOLATO LIGAND;

Crystal structure and two-photon absorption properties study of a new zinc complex constructed by DMIT ligand

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