COORDINATION COMPOUNDS OF TERT-BUTYLIMINOVANADIUM(V) TRICHLORIDE WITH O-DONOR-LIGANDS German

Preuss F.; Frank W.; Reiss G.Mullerbecker S.Hornung G.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >COORDINATION COMPOUNDS OF TERT-BUTYLIMINOVANADIUM(V) TRICHLORIDE WITH O-DONOR-LIGANDS German

【24h】

COORDINATION COMPOUNDS OF TERT-BUTYLIMINOVANADIUM(V) TRICHLORIDE WITH O-DONOR-LIGANDS German

机译：叔丁基亚甲基钒（V）三氯化物与O-供体配体的配位化合物德语

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reaction of tert-butyliminovanadium(V)trichloride (1) with cyclic and acyclic ethers, ethylene carbonate and thietane has been studied. The 1:1-complexes have a different stability; reversible and irreversible cleavage of ether in the coordination sphere of the vanadium atom rearranging in omega-chloroalkanolato ligands are observed. The reaction of 1 with 2-chloroethanol, 3-chloropropanol and 5-chloropentanol yields the complexes (C4H9N)-C-1 = V(OR)Cl-2 (R = CH2CH2CH2CH2CH2Cl) and C4H9N = V(OR)Cl-2 . ROH; in the presence of triethylamine the disubstituted compounds (C4H9N)-C-t = V(OR)(2)Cl are formed. The V-51 NMR spectra are discussed. The crystal structure of (C4H9N)-C-t = VCl3 . DME (12) and (C4H9N)-C-t = V(OCH2CH2Cl)Cl-2 . HOCH2CH2Cl (13) has been determined. The vanadium atoms in 13 have a distorted octahedral coordination and are linked by the oxygen atoms of the 2-chloroethanolato ligands forming a binuclear complex. In solution molecular weight measurement and V-51 NMR data indicate the equilibrium between a mononuclear complex 13 and its isomer (C4H9N)-C-t = V(OCH(2)CH(2)C1)(2)Cl . HCl. References: 17

机译：研究了叔丁基亚氨基钒（V）三氯化物（1）与环醚和无环醚、碳酸乙烯酯和硫杂环丁烷的反应。1：1 复合物具有不同的稳定性;观察到醚在omega-氯链烷醇配体中钒原子重排的配位球中的可逆和不可逆裂解。1 与 2-氯乙醇、3-氯丙醇和 5-氯戊醇反应产生络合物（C4H9N）-C-1 = V（OR）Cl-2 （R = CH2CH2CH2CH2CH2Cl）和 [C4H9N = V（OR）Cl-2 .ROH];在三乙胺存在下，形成二取代化合物（C4H9N）-C-t = V（OR）（2）Cl。讨论了V-51 NMR谱图。[（C4H9N）-C-t = VCl3 的晶体结构。DME] （12）和 [（C4H9N）-C-t = V（OCH2CH2Cl）Cl-2 .HOCH2CH2Cl]（13）已测定。13中的钒原子具有扭曲的八面体配位，并由2-氯乙醇配体的氧原子连接，形成双核配合物。在溶液中，分子量测量和 V-51 NMR 数据表明单核配合物 13 与其异构体 [（C4H9N）-C-t = V（OCH（2）CH（2）C1）（2）Cl .盐酸]。[参考文献： 17]

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第10期|1663-1671|共9页
作者
Preuss F.; Frank W.; Reiss G.Mullerbecker S.Hornung G.;
展开▼
作者单位

UNIV KAISERSLAUTERN FACHBEREICH CHEM ERWIN SCHRODINGER STR D-67663 KAISERSLAUTERN GERMANY;

展开▼
收录信息
原文格式 PDF
正文语种德语
中图分类化学;
关键词
Tert-butyliminovanadium(v) trichloride; Coordination compounds; H-1; c-13; v-51 nmr; Crystal structure; Molecular-structure; Complexes; Oxovanadium(v); Derivatives;

机译：三氯化叔丁基钒（v）;配位化合物;H-1;C-13;V-51 核磁共振;晶体结构;分子结构;复合物;氧代钒（v）;衍生物;

相似文献

外文文献
中文文献
专利

1. ChemInform Abstract: Thermal Properties of Solid Coordination Compounds. Part 2. Factors Influencing the Thermal Transformation of Solid Coordination Compounds [J] . O. CARP, E. SEGAL Chem Inform . 1998,第41期

机译：ChemInform Abstract: Thermal Properties of Solid Coordination Compounds. Part 2. Factors Influencing the Thermal Transformation of Solid Coordination Compounds
2. Synthesis of Some Mixed Coordination Complexes of Antimony Trichloride with Phenols, Acid Amides, Dimethyl Sulphoxide and Cyclopentadiene [J] . M.K. Rastogi Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry . 1984,第6期

机译：Synthesis of Some Mixed Coordination Complexes of Antimony Trichloride with Phenols, Acid Amides, Dimethyl Sulphoxide and Cyclopentadiene
3. Co(NCS)2 Chain Compound with Alternating 5- and 6‑Fold Coordination: Influence of Metal Coordination on the Magnetic Properties [J] . Böhme Michael, Rams Michał, Krebs ChristophMangelsen SebastianJess InkePlass WinfriedNäther Christian Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2022,第42期

机译：Co(NCS)2 Chain Compound with Alternating 5- and 6‑Fold Coordination: Influence of Metal Coordination on the Magnetic Properties
4. Clouds4Coordination: Managing Project Collaboration in Federated Clouds [C] . Ioan Petri, Omer Rana, Tom Beach, IEEE/ACM International Conference on Utility and Cloud Computing . 2015

机译：Clouds4Coordination：在联合云中管理项目协作
5. 以[2.2]對環芳建構的雙極性有機發光二極體材料 =[2.2]Paracyclophane-Based Ambipolar Compounds for Organic Light Emitting Diodes Application [D] . Hong, Jia-Jyun. 2018

机译：以[2.2]对环芳建构的双极性有机发光二极体材料 =[2.2]Paracyclophane-Based Ambipolar Compounds for Organic Light Emitting Diodes Application
6. Enantioselective cellular localisation of europium(iii) coordination complexes [O] . Andrew T. Frawley, Holly V. Linford, Matthieu Starck, 2018

机译：coordination（iii）配合物的对映选择性细胞定位
7. La territorialisation de la recherche et de l’innovation orientation, programmation et coordination (The territorialisation of research and innovation orientation, planning and coordination) [O] . Blandine LAPERCHE, Dimitri UZUNIDIS 100

机译：La territorialisation de la recherche et de l'innovation orientation，programmation et coordination（The zonelandial of research and innovation orientation，planning and coordination）
8. Heavy Ion Synchrotron and Cooler Ring at GSI (Gesellschaft fuer Schwerionenforschung m.b.H., Darmstadt, Federal Republic of Germany) [R] . Kienle, P. 1986

机译：GsI的重离子同步加速器和冷却器环（Gesellschaft fuer schwerionenforschung m.b.H.，Darmstadt，Germany of Germany）

COORDINATION COMPOUNDS OF TERT-BUTYLIMINOVANADIUM(V) TRICHLORIDE WITH O-DONOR-LIGANDS German

摘要

著录项

相似文献

相关主题

期刊订阅