首页> 外文期刊>journal of chemical physics >Analysis of torsional spectra of molecules with twoC3vinternal rotors. IV. The torsional potential function for propanehyphen;d0and hyphen;d3
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Analysis of torsional spectra of molecules with twoC3vinternal rotors. IV. The torsional potential function for propanehyphen;d0and hyphen;d3

机译:Analysis of torsional spectra of molecules with twoC3vinternal rotors. IV. The torsional potential function for propanehyphen;d0and hyphen;d3

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The Raman spectra of gaseous propanehyphen;d0and hyphen;d3have been recorded between 50 and 3500 cmminus;1. Considerable torsional data are reported and used to characterize the torsional potential function based on a semirigid model. The average rsquo;rsquo;effectiversquo;rsquo;V3for the propanes is found to be 1139plusmn;10 cmminus;1. The sinendash;sine coupling term is similar in magnitude but opposite in sign to the cosinendash;cosine coupling term in propanehyphen;d0.

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