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A correlation between NMR chemical shifts and Mouml;ssbauer quadrupole splittings for119Sn and125Te in organotin and organotellurium compounds

机译:A correlation between NMR chemical shifts and Mouml;ssbauer quadrupole splittings for119Sn and125Te in organotin and organotellurium compounds

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A correlation has been observed between solution NMR chemical shifts dgr;NMRand Mouml;ssbauer quadrupole splittings Dgr; for119Sn and125Te in a number of organotin and organotellurium compounds. These correlations are discussed in terms of the effects on dgr;NMRand Dgr; of the valencephyphen;orbital populations and the inverse cube of the radii of the 5pelectrons.

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