SYNTHESIS AND CRYSTAL STRUCTURE OF RB8P4N6(NH)(4)(NH2)(2) WITH THE ADAMANTANE-LIKE ANION P4N6(NH)(4)(6-) German

Golinski F.; Jacobs H.

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SYNTHESIS AND CRYSTAL STRUCTURE OF RB8P4N6(NH)(4)(NH2)(2) WITH THE ADAMANTANE-LIKE ANION P4N6(NH)(4)(6-) German

机译：RB8P4N6（NH）（4）（NH2）（2）与类金刚烷阴离子P4N6（NH）（4）（6-）的合成及晶体结构德语

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RbNH2 reacts with P3N5 (molar ratio 6:1) at 400 OC within 5 d to colourless Rb-8P4N6(NH)(4)(NH2)(2). Suitable crystals for a X-ray structure determination were obtained: Pnma, Z = 4, a = 17.643(9) Angstrom, b = 13.777(9) Angstrom, c = 8.422(3) Angstrom Z(F-o(2)) greater than or equal to 3 sigma(F-o(2)): 1143, Z(var.) = 98m R/R(w) = 0.038/0.045 The compound contains adamantane-like molecular anions P4N6(NH)(4)(6-). Their centres of gravity are arranged in a distorted hexagonal primitive array. All trigonal prisms of this array contain one amide ion. Rubidium ions connect the anions irregularly. References: 5

机译：RbNH2 在 400 OC 下与 P3N5 （摩尔比 6：1）反应 5 d 内生成无色 Rb-8[P4N6（NH）（4）]（NH2）（2）。获得了适合X射线结构测定的晶体：Pnma，Z=4，a=17.643（9）埃，b=13.777（9）埃，c=8.422（3）埃Z（F-o（2））大于或等于3sigma（F-o（2））：1143，Z（var.）=98m R/R（w）=0.038/0.045 该化合物含有类金刚烷分子阴离子[P4N6（NH）（4）]（6-）。它们的重心排列成一个扭曲的六边形原始阵列。该阵列的所有三角棱柱都包含一个酰胺离子。铷离子不规则地连接阴离子。[参考文献： 5]

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第1期|29-33|共5页
作者
Golinski F.; Jacobs H.;
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作者单位

UNIV DORTMUND FACHBEREICH CHEM POSTFACH 500500 D-44221 DORTMUND GERMANY;

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正文语种德语
中图分类化学;
关键词
Rubidium imido nitrido phosphate(v); Synthesis; Crystal structure;

机译：磷酸铷（v）;合成;晶体结构;

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1. ChemInform Abstract: Synthesis and Crystal Structure of Rb8(P4N6(NH)4)(NH2)2 with the Adamantane‐Like Anion (P4N6(NH)4)6‐. [J] . F. GOLINSKI, H. JACOBS Chem Inform . 1995,第20期

机译：ChemInform Abstract: Synthesis and Crystal Structure of Rb8(P4N6(NH)4)(NH2)2 with the Adamantane‐Like Anion (P4N6(NH)4)6‐.
2. ChemInform Abstract: Synthesis and Crystal Structure of Na10(P4(NH)6N4)(NH2)6(NH3)0.5 with an Adamantane‐Like Anion (P4(NH)6N4)4‐. [J] . H. JACOBS, S. POLLOK, F. GOLINSKI Chem Inform . 1994,第44期

机译：ChemInform Abstract: Synthesis and Crystal Structure of Na10(P4(NH)6N4)(NH2)6(NH3)0.5 with an Adamantane‐Like Anion (P4(NH)6N4)4‐.
3. ChemInform Abstract: Synthesis and Crystal Structure of Ammonium Tetraamminelithium Amidotrithiophosphate‐Ammonia(1/1) (NH4)Li(NH3)4 P(NH2)S3×NH3. [J] . Karin Pfisterer, Nikolaus Korber Chem Inform . 2002,第28期

机译：ChemInform Abstract: Synthesis and Crystal Structure of Ammonium Tetraamminelithium Amidotrithiophosphate‐Ammonia(1/1) (NH4)Li(NH3)4 P(NH2)S3×NH3.
4. アンモニア予混合火炎におけるNH*/NH2*自発光と当量比の相関 [C] . 樋野翔馬, 村井隆ー, 堀司燃焼シンポジウム . 2020

机译：NH * / NH2 *自排放与氨初始火焰的自排放和等同比之间的相关性
5. Regulated Membrane Localization of Tiam1 Mediated by the NH2-terminal Pleckstrin Homology Domain Is Required for Rac-dependent Membrane Ruffling and C-Jun NH2-terminal Kinase Activation [O] . Frits Michiels, Jord C. Stam, Peter L. Hordijk, 1997

机译：由Rac依赖的膜起皱和C-Jun NH2末端激酶激活需要由NH2末端Pleckstrin同源域介导的Tiam1调节的膜定位。
6. High-resolution energy-selected study of the reaction NH3+→NH2++H: Accurate thermochemistry for the NH2/NH2+ and NH3/NH3+ systems [O] . Y. Song, X.-M. Qian, K.-C. Lau, 2001

机译：高分辨率的能量选择对反应NH3 +→NH2 ++ H：NH2 / NH2 +和NH3 / NH3 +系统的准确热化学
7. Critical Evaluation of the Oscillator Strengths of NH2 and the Heats of Formation of NH and NH2 [R] . Anderson, W. R. 1988

机译：NH2振荡强度和NH和NH2生成热的临界评价

SYNTHESIS AND CRYSTAL STRUCTURE OF RB8P4N6(NH)(4)(NH2)(2) WITH THE ADAMANTANE-LIKE ANION P4N6(NH)(4)(6-) German

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