Preparation of polyaniline/TiO2 hybrid microwires in the microchannels of a template

Shanxin Xiong; Qi Wang; Yinghong Chen

首页> 外文期刊>Materials Chemistry and Physics >Preparation of polyaniline/TiO2 hybrid microwires in the microchannels of a template

【24h】

Preparation of polyaniline/TiO2 hybrid microwires in the microchannels of a template

机译：Preparation of polyaniline/TiO2 hybrid microwires in the microchannels of a template

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相关主题

摘要

Polyaniline (PANI)/TiO2 hybrid microwires with diameter of 160–180 nm were prepared through the sol–gel process of TiO2 and in situ polymerization of aniline in the microchannels of anodic aluminum oxide (AAO) template. The structure, morphology and properties of the microwires were characterized with scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), fluorescence spectroscopy (FL), ultraviolet–visible spectroscopy (UV–vis) and X-ray photoelectron spectroscopy (XPS). The results show that the regular arrangement of microwires, with well-dispersed inorganic phase in the organic matrix is formed. Also, the shape of the hybrid microwires is similar to that of the template channel and the diameter of microwires is smaller than that of the template channels due to the shrinkage of volume during the sol–gel process. XPS analysis confirms that there are a lot of leftover OH groups in the hybrid system owing to the lower treatment temperature of TiO2 gel and interactions between PANI and TiO2, which is consistent with the results of UV–vis and FL analysis. The XRD data confirms that no obvious diffraction peak is observed in hybrid microwires at the reported treatment temperature (180 °C). FL spectra shows that the interaction and energy band match between PANI and TiO2 cause in the blue shift of the emission peaks of hybrid microwires. It is obvious that with the applied approach, the organic/inorganic hybrid materials with slight phase separation, equable distribution, well-ordered structure and unique function can be prepared easily.

著录项

来源
《Materials Chemistry and Physics》 |2007年第3期|450-455|共6页
作者
Shanxin Xiong; Qi Wang; Yinghong Chen;
展开▼
作者单位

Temasek Laboratories of Nanyang Technological University, 50 Nanyang Drive, 637553 Singapore, Singapore;

State Key Laboratory of Polymer Materials Engineering (Sichuan University), Polymer Research Institute of Sichuan University, Chengdu 610065, China;

展开▼
收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类工程材料学;
关键词
Template synthesis; Microwires; Polyaniline; Hybrid;

Preparation of polyaniline/TiO2 hybrid microwires in the microchannels of a template

摘要

著录项

相关主题

期刊订阅