The theoretical and experimental investigations of first hyperpolarizabilities for azo chromophores—Derivatives of bisphenol A

Irmina Zadrozna; Ewa Kaczorowska

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The theoretical and experimental investigations of first hyperpolarizabilities for azo chromophores—Derivatives of bisphenol A

机译：The theoretical and experimental investigations of first hyperpolarizabilities for azo chromophores—Derivatives of bisphenol A

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摘要

In this paper we report a synthesis of a series of nonlinear optical donor–acceptor chromophores, derivatives of bisphenol A. The studied compounds contain azo bonds with substituted thiazole ring as side groups. Their molecular first hyperpolarizablities were measured by solvatochromic method. The experimental values were compared with the results of semi-empirical calculations. The structures of obtained compounds were confirmed by infrared, 1H NMR and ultraviolet spectroscopy. Design of nonlinear-optical polymers with included chromophores was also performed.

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来源
《Materials Chemistry and Physics》 |2007年第3期|465-469|共5页
作者
Irmina Zadrozna; Ewa Kaczorowska;
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作者单位

Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw, Poland;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类工程材料学;
关键词
Optical materials; Organic compounds; Semi-empirical calculations;

The theoretical and experimental investigations of first hyperpolarizabilities for azo chromophores—Derivatives of bisphenol A

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