ORGANOMETALLIC COMPOUNDS OF THE LANTHANIDES .88. MONOMERIC LANTHANIDE(III) AMIDES - SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF ND(N(C6H5)(SIME(3)))(3)(THF), LI(THF)(2)(MU-CL)(2)ND(N(C(6)H(3)ME(2)-2,6)(SIME(3)))(2)(THF), AND CLND(N(C6H3-ISO-PR-2-2,

Schumann H.; Rosenthal ECE.; Hemling H.Esser L.Winterfeld J.

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ORGANOMETALLIC COMPOUNDS OF THE LANTHANIDES .88. MONOMERIC LANTHANIDE(III) AMIDES - SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF ND(N(C6H5)(SIME(3)))(3)(THF), LI(THF)(2)(MU-CL)(2)ND(N(C(6)H(3)ME(2)-2,6)(SIME(3)))(2)(THF), AND CLND(N(C6H3-ISO-PR-2-2,

机译：镧系元素的有机金属化合物 .88.单体镧系元素（III）酰胺 - ND（N（C6H5）（SIME（3）））（3）（THF）、LI（THF）（2）（MU-CL）（2）ND（N（C（6）H（3）ME（2）-2,6）（SIME（3）））（2）（THF）和CLND（N（C6H3-ISO-PR-2-2，

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A series of lanthanide(III) amides Ln{N(C6H5). (SiMe(3))}(3)(THF)(x) Ln = Y (1), La (2), Nd (3), Sm (4), Eu (5), Tb (6), Er (8), Yb (9), Lu (10) could be prepared by the reaction of lanthanide trichlorides, LnCl(3) with LiN(C6H5)(SiMe(3)). Treatment of NdCl3(THF)(2) and LuCl3(THF)(3) with the lithium salts of the bulky amides N(C(6)H(3)R(2)-2,6)(SiMe(3)) - (R = Me, iso-Pr) results in the formation of the lanthanide diamidesLi(THF)(2)(mu-Cl)(2)Nd{N(C(6)H(3)Me(2)-2,6)(SiMe(3))}(2)(THF) (11) and ClLn{N(C6H3-iso-Pr-2-2,6)(SiMe(3))}(2)(THF) Ln = Nd (12), Lu (13), respectively. The H-1- and C-13-NMR and mass spectra of the new compounds as well as the X-ray crystal structures of the neodymium derivatives 3, 11 and 12 are discussed. References: 26

机译：一系列镧系元素（III）酰胺[Ln{N（C6H5）。（SiMe（3））}(3)（四氢呋喃）（x）][Ln=Y（1），La（2），Nd（3），Sm（4），Eu（5），Tb（6），Er（8），Yb（9），Lu（10）]可以通过三氯化镧系元素LnCl（3）与LiN（C6H5）（SiMe（3））反应制得。用大块酰胺[[N（C（6）H（3）R（2）-2,6）（SiMe（3））]-（R=Me，iso-Pr））的锂盐处理NdCl3（THF）（2）和LuCl3（THF）（3）]-（R=Me，iso-Pr）导致镧系元素二酰胺[Li（THF）（2）（mu-Cl）（2）Nd{N（C（6）H（3）Me（2）-2,6）（SiMe（3）））}（2）（THF）]（11）和[ClLn{N（C6H3-iso-Pr-2-2，6）（SiMe（3））}（2）（THF）] [Ln = Nd （12）， Lu （13）]。讨论了新化合物的H-1-和C-13-NMR和质谱，以及钕衍生物3、11和12的X射线晶体结构。[参考文献： 26]

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第1期|122-130|共9页
作者
Schumann H.; Rosenthal ECE.; Hemling H.Esser L.Winterfeld J.;
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TECH UNIV BERLIN INST ANORGAN & ANALYT CHEM SEKR C2 STR 17 JUNI 135 D-10623 BERLIN GERMANY;

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中图分类化学;
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Lanthanide(iii)amides; (trimethylsilylamido)lanthanide(iii) complexes; X-ray structures; Molecular-structure; Complexes; Neodymium; Coordination; Cyclopentadienyl; Alkoxides; Yttrium; Ligands;

机译：镧系（iii）酰胺;（三甲基硅酰胺基）镧系元素（III）络合物;X射线结构;分子结构;复合物;钕;协调;环戊二烯基;醇盐;钇;配;

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1. Monomere Lanthanoid(III)-amide: Synthese und Röntgenstrukturanalyse von [Nd{N(C_6H_5)(SiMe_3)}_3(THF)], [Li(THF)_2(μ-Cl)_2Nd{N(C_6H_3Me_2-2,6)(SiMe_3)}_2(THF)] und [ClNd{N(C_6H_3-iso-Pr_2-2,6)(SiMe_3)}_2 [J] . Herbert Schumann, Jouml, rn Winterfeld, Zeitschrift fur Anorganische und Allgemeine Chemie . 1995,第1期

机译：单体镧系元素（III）酰胺：[Nd {N（C_6H_5）（SiMe_3）} _ 3（THF）]，[Li（THF）_2（μ-Cl）_2Nd {N（C_6H_3Me_2-2,6）的合成和X射线结构分析（SiMe_3）} _ 2（THF）]和[ClNd {N（C_6H_3-iso-Pr_2-2.6）（SiMe_3）} _ 2
2. SYNTHESIS, X-RAY CRYSTAL STRUCTURE DETERMINATION, AND NMR SPECTROSCOPIC INVESTIGATION OF TWO HOMOLEPTIC FOUR-COORDINATE LANTHANIDE COMPLEXES - TRIVALENT ((T)BU(2)P(2))(2)LA(MU-P(T)BU(2))(2)LI(THF) AND DIVALENT YB(MU-P(T)BU(2))(2)LI(THF)(2) [J] . Rabe GW., Schier A., Riede J. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1996,第1期

机译：SYNTHESIS, X-RAY CRYSTAL STRUCTURE DETERMINATION, AND NMR SPECTROSCOPIC INVESTIGATION OF TWO HOMOLEPTIC FOUR-COORDINATE LANTHANIDE COMPLEXES - TRIVALENT ((T)BU(2)P(2))(2)LA(MU-P(T)BU(2))(2)LI(THF) AND DIVALENT YB(MU-P(T)BU(2))(2)LI(THF)(2)
3. PHOSPHIDO COMPLEXES OF THE LANTHANIDES - SYNTHESIS AND X-RAY CRYSTAL STRUCTURE DETERMINATION OF A TRIS(PHOSPHIDO) SPECIES OF NEODYMIUM - NDP(SIME(3))(2)(3)(THF)(2) [J] . Rabe GW., Ziller JW. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第21期

机译：PHOSPHIDO COMPLEXES OF THE LANTHANIDES - SYNTHESIS AND X-RAY CRYSTAL STRUCTURE DETERMINATION OF A TRIS(PHOSPHIDO) SPECIES OF NEODYMIUM - NDP(SIME(3))(2)(3)(THF)(2)
4. Synthesis and Structures of Aluminum and Magnesium Complexes of Tetraimidophosphates and Trisamidothiophosphates: EPR and DFT Investigations of the Persistent Neutral Radicals {Me2Al[(μ-NR)(μ-NtBu)P(μ-NtBu)2]Li(THF)2}• (R = SiMe3, tBu) [O] . Armstrong, Andrea, Chivers, Tristram, Tuononen, Heikki, 2015

机译：四亚氨基磷酸酯和三氨基硫代磷酸铝和镁配合物的合成和结构：持久性中性基团{Me2Al [（μ-NR）（μ-NtBu）P（μ-NtBu）2] Li（THF）2的EPR和DFT研究）（R = SiMe3，tBu）
5. Isolation and X-ray Crystal Structures of Li mu 2-As(SiMe3)2MU 3-As(SiMe3)2(THF)2and (Me3Si)2AsLi(THF)22 [R] . Jones, L. T., McPhail, A. T., Wells, R. L. 1994

机译：Li mu 2-as（sime3）2mU 3-as（sime3）2（THF）2和（me3si）2asLi（THF）22的分离和X射线晶体结构

ORGANOMETALLIC COMPOUNDS OF THE LANTHANIDES .88. MONOMERIC LANTHANIDE(III) AMIDES - SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF ND(N(C6H5)(SIME(3)))(3)(THF), LI(THF)(2)(MU-CL)(2)ND(N(C(6)H(3)ME(2)-2,6)(SIME(3)))(2)(THF), AND CLND(N(C6H3-ISO-PR-2-2,

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