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首页> 外文期刊>Journal of Applied Polymer Science >Preparation of a functional reduced graphene oxide and carbon nanotube hybrid and its reinforcement effects on the properties of polyimide composites
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Preparation of a functional reduced graphene oxide and carbon nanotube hybrid and its reinforcement effects on the properties of polyimide composites

机译：Preparation of a functional reduced graphene oxide and carbon nanotube hybrid and its reinforcement effects on the properties of polyimide composites

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摘要

The homogeneous dispersion and strong interfacial interactions of carbon nanomaterials are vital factors on enhancing the properties of polymer composites. Two-dimensional reduced graphene oxide (rGO) and one-dimensional carbon nanotubes (CNTs) were first grafted by 4,4'-oxydianiline (ODA). The successful grafting of ODA onto the rGO and CNTs were confirmed by Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The hybrid carbon nanomaterials of the functionalized CNTs and rGO with different ratios were prepared via a solution-mixing method, and their dispersion state was investigated. The hybrid carbon nanomaterials with good stability were introduced to polyimide (PI) via in situ polymerization. The morphology and properties of the polymer composites were studied. The results show that much better mechanical and electrical properties of the composites could be achieved in comparison with those of the neat PI. An improvement of 100.7 on the tensile strength and eight orders for the electrical conductivity were achieved at only a 1.0 wt hybrid content. A significant enhancement effect was attributed to the homogeneous dispersion of the filler, filler-matrix strong interfacial interactions, and unique structure of the hybrid carbon nanomaterials in the composites. (C) 2016 Wiley Periodicals, Inc.

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