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Pressurehyphen;broadened infrared linewidths of HF:Ar and HCl:Ar at moderate densities

机译:Pressurehyphen;broadened infrared linewidths of HF:Ar and HCl:Ar at moderate densities

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The widths of several HCl and HF absorption lines broadened by 10 to 140 atm of argon have been measured using a tunable optical parametric oscillator. The lower pressure data yield values for the linear pressurehyphen;broadening coefficients. The data taken at higher densities are used to obtain corrections to the linewidth which are second order in the density. These second density effects are compared with a formal theory for the absorption coefficient at moderate densities due to Albers and Oppenheim, as well as with measurements of the diffusion coefficient obtained in other experiments.

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