SYNTHESIS AND CRYSTAL STRUCTURE OF PRASEODYMIUM PROPIONATE TRIHYDRATE, PR(CH3CH2COO)(3)(H2O)(3) German

Deiters D.; Meyer G.

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SYNTHESIS AND CRYSTAL STRUCTURE OF PRASEODYMIUM PROPIONATE TRIHYDRATE, PR(CH3CH2COO)(3)(H2O)(3) German

机译：丙酸镨三水合物PR（CH3CH2COO）（3）（H2O）（3）的合成及晶体结构德语

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Single crystals of Pr(CH3CH2COO)(3)(H2O)(3) were obtained by dissolving freshly prepared praseodymium hydroxide in diluted propionic acid. The crystal structure (monoclinic, P2(1)/c, Z = 4, a = 1034.2(2) pm, b = 1521.2(3) pm, c = 2086.3(7) pm, beta = 102.87(2)degrees, R1 = 0.0864, wR2 = 0.1196) consists of one-dimensional infinite chains parallel 010. Pr1 and Pr2 are coordinated by four tridentate-bridging propionate groups. Additionally, Pr1 is coordinated by three ''coordination water'' molecules, Pr2 by two bidentate propionate groups. There are, in addition, three ''crystal water'' molecules so that praseodymium propionate trihydrate should be formulated as (H2O)(3)Pr1(CH3CH2COO)(4)Pr2(CH3CH2COO)(2) (H2O)(3). References: 18

机译：将新鲜制备的氢氧化镨溶解在稀的丙酸中，得到Pr（CH3CH2COO）（3）（H2O）（3）的单晶。晶体结构（单斜晶系，P2（1）/c，Z=4，a=1034.2（2）pm，b=1521.2（3）pm，c=2086.3（7）pm，beta=102.87（2）度，R1=0.0864，wR2=0.1196）由平行的一维无限链组成[010]。Pr1 和 Pr2 由四个三齿桥接丙酸酯基团配位。此外，Pr1 由三个“配位水”分子配位，Pr2 由两个双酸丙酸酯基团配位。此外，还有三个“结晶水”分子，因此丙酸镨三水合物应配制成[（H2O）（3）Pr1（CH3CH2COO）（4）Pr2（CH3CH2COO）（2）] （H2O）（3）。[参考资料： 18]

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1996年第2期|325-328|共4页
作者
Deiters D.; Meyer G.;
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作者单位

UNIV HANNOVER INST ANORGAN CHEM CALLINSTR 9 D-30167 HANNOVER GERMANY;

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原文格式 PDF
正文语种德语
中图分类化学;
关键词
Praseodymium; Propionate; Crystal structure;

机译：镨;丙酸盐;晶体结构;

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1. Synthesis and Crystal Structure of a Novel 1D Coordination Polymer:Pr(BYBA)3(H2O)2 Pr(BYBA)3(H2O) [J] . SUN Rui-Qing, CAO Yan-Ning, ZHANG Han-Hui Chinese journal of structural chemistry . 2007,第11期

机译：Synthesis and Crystal Structure of a Novel 1D Coordination Polymer:Pr(BYBA)3(H2O)2 Pr(BYBA)3(H2O)
2. Crystal structures of ethylenediaminetetraacetato metal complexes. III. Hexaaquamagnesium(II) aquaethylenediaminetetraacetatocadmium(II) trihydrate, (H2O)6Mg(C10H12N2O8)(H2O)Cdn.3nH2O [J] . X. Solans, S. Galí, M. Font‐AltabaJ. OlivaJ. Herrera Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications . 1983,第4期

机译：Crystal structures of ethylenediaminetetraacetato metal complexes. III. Hexaaquamagnesium(II) aquaethylenediaminetetraacetatocadmium(II) trihydrate, (H2O)6Mg(C10H12N2O8)(H2O)Cdn.3nH2O
3. ChemInform Abstract: Pr2Te2O7: A Praseodymium(III) Oxide Oxotellurate(IV) According to Pr2O(TeO3)2with Pyrochlore‐Type Crystal Structure. [J] . Frank A. Weber, Thomas Schleid Chem Inform . 2000,第38期

机译：ChemInform Abstract: Pr2Te2O7: A Praseodymium(III) Oxide Oxotellurate(IV) According to Pr2O(TeO3)2with Pyrochlore‐Type Crystal Structure.
4. Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture [O] . Zhu Yan-Yu, Sun Zhen-Gang, Tong Fei, 2011

机译：Hydrothermal synthesis, crystal structures, and luminescent properties of a series of new lanthanide oxalatophosphonates with a layer architecture

SYNTHESIS AND CRYSTAL STRUCTURE OF PRASEODYMIUM PROPIONATE TRIHYDRATE, PR(CH3CH2COO)(3)(H2O)(3) German

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