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>Vibrational relaxation and small rsquo;rsquo;bubblersquo;rsquo; spectroscopy of the NO 3ssgr; (A2Sgr;+) Rydberg state in solid rare gases
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Vibrational relaxation and small rsquo;rsquo;bubblersquo;rsquo; spectroscopy of the NO 3ssgr; (A2Sgr;+) Rydberg state in solid rare gases
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机译：Vibrational relaxation and small rsquo;rsquo;bubblersquo;rsquo; spectroscopy of the NO 3ssgr; (A2Sgr;+) Rydberg state in solid rare gases
The 1933 Aring; ArF excimer laser has been used to excite NO 3ssgr; Rydberg fluorescence in solid rare gases. A comparison of Rydberg and valence spectra indicates that Rydberg fluorescence is particularly sensitive to the nature of the local environment. The data demonstrate the limits of a continuum host approximation in the small rsquo;rsquo;bubblersquo;rsquo; model. All observed emission is vibrationally relaxed. The relaxation rates appear to be many orders of magnitude faster than observed for ground state diatomics with equivalent vibrational quanta.
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