EPR studies of xhyphen;ray damaged crystals of (NH4)2SO4show that long lived defects, NH3+ions, are produced in two inequivalent sites with each site having two magnetically inequivalent orientations. All sites have approximately the same isotropic hyperfine splittings which are found to be 19.0 G for nitrogen and minus;24.6 G for hydrogen. The anisotropic components are different for the two inequivalent sites indicating different amounts of restricted rotation for the two sites. A second transient defect is identified as SO3minus;.
展开▼