MAGNESIUM PHTHALOCYANINES - SYNTHESIS AND PROPERTIES OF HALOPHTHALOCYANINATOMAGNESATE, MG(X)PC(2-)(-) (X=F, CL, BR) - CRYSTAL STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)IMINIUMCHLORO-(PHTHALOCYANINATO)MAGNESATE ACETONE SOLVATE German

Assmann B.; Lehmann G.; Homborg H.Ostendorp G.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >MAGNESIUM PHTHALOCYANINES - SYNTHESIS AND PROPERTIES OF HALOPHTHALOCYANINATOMAGNESATE, MG(X)PC(2-)(-) (X=F, CL, BR) - CRYSTAL STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)IMINIUMCHLORO-(PHTHALOCYANINATO)MAGNESATE ACETONE SOLVATE German

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MAGNESIUM PHTHALOCYANINES - SYNTHESIS AND PROPERTIES OF HALOPHTHALOCYANINATOMAGNESATE, MG(X)PC(2-)(-) (X=F, CL, BR) - CRYSTAL STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)IMINIUMCHLORO-(PHTHALOCYANINATO)MAGNESATE ACETONE SOLVATE German

机译：酞菁镁 - 卤酞菁原子镁酸盐 MG（X）PC（2-）（-）（X=F， CL， BR） - 双（三苯基膦）亚胺氯-（酞菁）镁丙酮溶剂化物的晶体结构德语

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Magnesium phthalocyanine reacts with excess tetra(n-butyl)ammonium- or bis(triphenylphosphine)iminiumhalide (((n)Bu(4)N)X or (PNP)X; X = F, Cl, Br) yielding halophthalocyaninatomagnesate (Mg(X)Pc(2-)(-); X = F, Cl, Br), which crystallizes in part as a scarcely soluble ((n)Bu(4)N) or (PNP) complex-salt. Single-crystal X-ray diffraction analysis of (b)(PNP)Mg(Cl)Pc(2-) . CH3COCH3 reveals that the Mg atom has a tetragonal pyramidal coordination geometry with the Mg atom displaced out of the center (Ct) of the inner nitrogen atoms (N-iso) of the nonplanar Pc ligand toward the Cl atom (d(Mg-Ct)= 0.572(3) Angstrom; d(Mg-Cl) = 2.367(2) Angstrom). The average Mg-N-iso distance is 2.058 Angstrom. Pairs of partially overlapping anions are present. The cation adopts a bent conformation ((b)(PNP)(+): d(P1-N(K))= 1.568(3) Angstrom; d(P2-N(K)) = 1.587(3) Angstrom; less than with right parenthesis(P1-N(K)-P2) = 141.3(2)degrees). Electrochemical and spectroscopic properties are discussed. References: 29

机译：酞菁镁与过量的四（正丁基）铵或双（三苯基膦）卤化亚胺（（（n）Bu（4）N）X或（PNP）X;X = F， Cl， Br）产生盐酞菁原子镁酸酯（[Mg（X）Pc（2-）]（-）;X = F， Cl， Br），部分结晶为几乎不溶的（（n）Bu（4）N）或（PNP）络合盐。（b）（PNP）[Mg（Cl）Pc（2-）]的单晶X射线衍射分析.CH3COCH3表明，Mg原子具有四边锥体配位几何形状，Mg原子从非平面Pc配体的内部氮原子（N-iso）的中心（Ct）向Cl原子移动（d（Mg-Ct）= 0.572（3）埃;d（Mg-Cl）= 2.367（2）埃）。平均 Mg-N-iso 距离为 2.058 埃。存在成对的部分重叠的阴离子。阳离子采用弯曲构象（（b）（PNP）（+）：d（P1-N（K））= 1.568（3）埃;d（P2-N（K））=1.587（3）埃;小于右括号（P1-N（K）-P2）=141.3（2）度）。讨论了电化学和光谱性质。[参考文献： 29]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1996年第6期|1085-1090|共6页
作者
Assmann B.; Lehmann G.; Homborg H.Ostendorp G.;
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CHRISTIAN ALBRECHTS UNIV KIEL INST ANORGAN CHEM OLSHAUSENSTR 40 D-24098 KIEL GERMANY;

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正文语种德语
中图分类化学;
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Magnesium compound; Phthalocyanine complex; Crystal structure; Vibrational spectra; Derivatives; Scattering; Porphyrin; Complexes;

机译：镁化合物;酞菁络合物;晶体结构;振动光谱;衍生品;散射;卟啉;配合物;

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机译：SYNTHESIS AND MAGNETIC PROPERTIES OF SIX NEW TRINUCLEAR OXO-CENTERED MANGANESE COMPLEXES OF GENERAL FORMULA MN3O(X-BENZOATO)(6)L-3 (X=2-F, 2-CL, 2-BR, 3-F, 3-CL, 3-BR L EQUALS PYRIDINE OR WATER) AND CRYSTAL STRUCTURES OF THE 2-F, 3-CL, AND 3-BR COM

MAGNESIUM PHTHALOCYANINES - SYNTHESIS AND PROPERTIES OF HALOPHTHALOCYANINATOMAGNESATE, MG(X)PC(2-)(-) (X=F, CL, BR) - CRYSTAL STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)IMINIUMCHLORO-(PHTHALOCYANINATO)MAGNESATE ACETONE SOLVATE German

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