REACTIONS OF ALCOHOLS AND MERCAPTANS WITH TETRAPHOSPHORUS TRICHALCOGENIDE DIIODIDES German

Blachnik R.; Baldus HP.; Tattershall BW.Peukert U.

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REACTIONS OF ALCOHOLS AND MERCAPTANS WITH TETRAPHOSPHORUS TRICHALCOGENIDE DIIODIDES German

机译：醇类和硫醇与四磷三硫族化物二碘化物的反应德语

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alpha-P(4)E(3)(I)R and alpha-P(4)E(3)R(2) (R = -OCH3, -OC2H5, -OCH(CH3)(2), -OC(CH3)(3) and -OC6H5) have been detected in the reaction solutions of alpha-P(4)E(3)I(2) (E = S, Se) with alcohols in the presence of triethylamine, or with trimethyltin alkoxides in CS2. beta-P4S3I2 reacted with methanol at 243 K in CS2 to yield beta-P4S3(I)OCH3, beta-P4S3(OCH3)(exo)(OCH3)(endo), and beta-P4S3(OCH3)(exo)(2). The thiolates alpha-P(4)Se(3)R(2)' (R' = -SC2H5, -n-SC5H11, -n-SC7H15, -SC(CH3)(3) and -SC6H5) were found in reaction solutions of alpha-P4Se3(2) with thiols HR'. The P-31 NMR data of these compounds are given. References: 19

机译：α-P（4）E（3）（I）R和α-P（4）E（3）R（2）（R = -OCH3、-OC2H5、-OCH（CH3）（2）、-OC（CH3）（3）和-OC6H5）在三乙胺存在下与醇的反应溶液中检测到，或在CS2中与三甲基锡醇盐的反应溶液中检测到α-P（4）E（3）（I）R和α-P（4）E（3）R（2）（R = -OCH3、-OC2H5、-OCH（CH3）（2）、-OC（CH3）（3）和-OC6H5）。β-P4S3I2 在 CS2 中与甲醇在 243 K 下反应生成 β-P4S3（I）OCH3、β-P4S3（OCH3）（exo）（OCH3）（endo）和 β-P4S3[（OCH3）（exo）]（2）。α-P4Se3]（2）与硫醇HR'的反应溶液中发现了硫代化物α-P（4）Se（3）R（2）' （R' = -SC2H5， -n-SC5H11， -n-SC7H15， -SC（CH3）（3） and -SC6H5）。给出了这些化合物的P-31 NMR数据。[参考文献： 19]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1996年第6期|958-964|共7页
作者
Blachnik R.; Baldus HP.; Tattershall BW.Peukert U.;
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UNIV OSNABRUCK INST CHEM ANORG CHEM POSTFACH 4469 D-49069 OSNABRUCK GERMANY;

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正文语种德语
中图分类化学;
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31p nmr spectroscopy; Phosphorus compounds; 3-iod-5-methoxy-2; 6; 7-trithia-1; 3; 4; 5-tetraphospha-bicyclo2; 2; 1; heptan; 5-dimethoxy-2; 3-iod-6-alkoxy-2; 5; 7 trichalkogena-1; 6-tetraphospha-bicyclo2; 1heptan; 6-dialkoxy(alkyl-thio)-2; 7-chalkogena-1; h; Eptan; Magnetic-resonance parameters; Trisulfide; Nmr;

机译：31p NMR波谱;磷化合物;3-碘-5-甲氧基-2;6;7-三硫杂-1;3;4;5-四磷杂双环[2;2;1;]庚烷;5-二甲氧基-2;3-碘-6-烷氧基-2;5;7 三白粒-1;6-四磷杂双环[2;1]庚烷;6-二烷氧基（烷基硫代）-2;7-白垩基因-1;]h;艾普坦;磁共振参数;三硫化物;核磁共振;

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1. ChemInform Abstract: α‐Tetraphosphorus Trichalcogenide Diiodide Compounds Containing Both Sulfur and Selenium. [J] . R. BLACHNIK, P. LOENNECKE, B. W. TATTERSHALL Chem Inform . 1993,第5期

机译：ChemInform Abstract: α‐Tetraphosphorus Trichalcogenide Diiodide Compounds Containing Both Sulfur and Selenium.
2. ChemInform Abstract: A Novel Synthetic Approach to β‐Arylselenenyl Tertiary Alcohols by the One‐Pot Reaction of Chloromethyl Selenides and Ketones Promoted by Samarium Diiodide. [J] . X. HUANG, D.‐H. DUAN Chem Inform . 1999,第8期

机译：ChemInform Abstract: A Novel Synthetic Approach to β‐Arylselenenyl Tertiary Alcohols by the One‐Pot Reaction of Chloromethyl Selenides and Ketones Promoted by Samarium Diiodide.
3. ChemInform Abstract: Oxidative Addition of Alkyl Halides to Rhodium(I) and Iridium(I) Dicarbonyl Diiodides: Key Reactions in the Catalytic Carbonylation of Alcohols [J] . P. R. ELLIS, J. M. PEARSON, A. HAYNESH. ADAMSN. A. BAILEYP. M. MAITLIS Chem Inform . 1995,第3期

机译：ChemInform Abstract: Oxidative Addition of Alkyl Halides to Rhodium(I) and Iridium(I) Dicarbonyl Diiodides: Key Reactions in the Catalytic Carbonylation of Alcohols

REACTIONS OF ALCOHOLS AND MERCAPTANS WITH TETRAPHOSPHORUS TRICHALCOGENIDE DIIODIDES German

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