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Product state and kinetic energy distributions in the ultraviolet photodissociation of the NOndash;Ar van der Waals molecule

机译:Product state and kinetic energy distributions in the ultraviolet photodissociation of the NOndash;Ar van der Waals molecule

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The internal state and kinetic energy distributions of theXtilde; NO fragments formed from the ultraviolet photodissociation of the NOndash;Ar van der Waals species were obtained by laserhyphen;excited fluorescence techniques. The initially excitedAtilde; NOndash;Ar rapidly dissociates to formXtilde; NO with little rotational excitation, with vibrational excitation determined by a Franckndash;Condon process, with a cos2thinsp;thgr; angular flux distribution (thgr; defined relative to the direction of polarization of the pump laser), and with a speedvsim;4.4times;105cm/s.

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