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首页> 外文期刊>Journal of thermal analysis and calorimetry >Thermal transformations of Cu–Mg (Zn)–Al(Fe) hydrotalcite-like materials into metal oxide systems and their catalytic activity in selective oxidation of ammonia to dinitrogen
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Thermal transformations of Cu–Mg (Zn)–Al(Fe) hydrotalcite-like materials into metal oxide systems and their catalytic activity in selective oxidation of ammonia to dinitrogen

机译：Thermal transformations of Cu–Mg (Zn)–Al(Fe) hydrotalcite-like materials into metal oxide systems and their catalytic activity in selective oxidation of ammonia to dinitrogen

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摘要

Layered double hydroxides (LDHs) containing Mg~(2+), Cu~(2+) or Zn~(2+) cations in the Me~(II) positions and Al~(3+) and Fe~(3+) in the Me~(III) positions were synthesized by coprecipitation method. Detailed studies of thermal transformation of obtained LDHs into metal oxide systems were performed using high temperature X-ray diffraction in oxidising and reducing atmosphere, thermogravimetry coupled with mass spectrometry and temperature-programmed reduction. The LDH samples calcined at 600 and 900 ?C were tested in the role of catalysts for selective oxidation of ammonia into nitrogen and water vapour. It was shown that all copper congaing samples presented high catalytic activity and additionally, for the Cu–Mg–Al and Cu–Mg–Fe hydrotalcite samples calcined at 600 ?C relatively high stability and selectivity to dinitrogen was obtained. An increase in calcination temperature to 900 ?C resulted in a decrease of their catalytic activity, possibly due to formation of well-crystallised metal oxide phases which are less catalytically active in the process of selective oxidation of ammonia.

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