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Role of rotational thermal bath excitation on the EPR transient regime: A theoretical discussion

机译:Role of rotational thermal bath excitation on the EPR transient regime: A theoretical discussion

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The excitation of rotational thermal baths can result in longhyphen;lived effects on spin relaxation in the slow motional region. An attempt at obtaining their quantitative evaluation is successfully made by enriching the Morindash;Kivelsonndash;Ogan (MKO) theory through comparison with the Kubondash;Freed (KF) one andviceversa. This comparison, in turn, is allowed by suitably extending the MKO theory so as to deal with spin excitation by external radiation fields. The MKO, furthermore, is limited to the secondhyphen;order Mori truncation while the KF one is related to the twohyphen;jump case. It is shown, then, that in the usual kind of steadyhyphen;state experiments, the MKO theory provides the same result as the KF one. In contrast, when spin relaxation is monitored in the presence of a fluctuating force whose time average intensity is not vanishing, the two theories can result in quite different physical effects.

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