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Rotational optical activity

机译:Rotational optical activity

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Optical activity generated by the rotational normal coordinates is investigated. The theoretical formulation is based on classical principles and uses the definition of the rotational normal coordinates and the changes in electric and magnetic dipole moment components along the principal axes of inertia due to rotations represented by these coordinates. It is assumed that the effective atomic charges and polarizabilities are uneffected during the rotational motions of the molecule.

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