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>Stark Effect and Hyperfine Splitting for Nearhyphen;Degenerate Levels of an Asymmetric Rotor. Application to NO2Cl and NOBr
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Stark Effect and Hyperfine Splitting for Nearhyphen;Degenerate Levels of an Asymmetric Rotor. Application to NO2Cl and NOBr
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机译：Stark Effect and Hyperfine Splitting for Nearhyphen;Degenerate Levels of an Asymmetric Rotor. Application to NO2Cl and NOBr
An approximate method is presented for calculating the Stark effect and hyperfine splitting of nearhyphen;degenerate rotational levels of an asymmetrichyphen;top molecule. This method has been used to calculate the Stark effects for the 21rarr;30transition of NO2Cl and the 11rarr;20transition of NOBr. The results are compared with the measured spectra and are found to agree within experimental error. The dipole moments obtained are mgr; = 0.53 D for NO2Cl and mgr;a= 1.80 D for NOBr. The component mgr;bfor NOBr cannot be determined from the spectrum.
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