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Photodissociation dynamics of a hydrogen molecule via superexcited states as studied through the angularhyphen;momentum population of an excited hydrogen atom

机译:Photodissociation dynamics of a hydrogen molecule via superexcited states as studied through the angularhyphen;momentum population of an excited hydrogen atom

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Photodissociation dynamics of a hydrogen molecule via vibrationally excited superexcited states has been studied through the angularhyphen;momentum population of an excited hydrogen atom with the principal quantum number 3. The population shows a strong dependence on the incident photon wavelength in the longer wavelength region and a weak dependence in the shorter wavelength region. The population seems to converge to the equal partition as the incident photon wavelength becomes shorter. It is shown that the Rosenndash;Zenerhyphen;type transition between the three states, not two states, at a large internuclear distance plays an important role in the dissociation dynamics. A close multilevel problem should be remarked even for a simple system such as a hydrogen molecule.

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