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机译:Selective deuteration illuminates the importance of tunneling in the unimolecular decay of Criegee intermediates to hydroxyl radical products
Univ Penn, Dept Chem, Philadelphia, PA 19104 USA;
Argonne Natl Lab, Chem Sci & Engn Div, 9700 S Cass Ave, Argonne, IL 60439 USA;
Criegee intermediates; unimolecular decay; quantum mechanical tunneling; kinetic isotope effect; atmospheric chemistry;