The microscopic properties of the inner surface of the cavities of Anopore and Nuclepore membranes are investigated with scanning electron microscopy (SEM), nitrogen adsorption isotherms, and deuterium nuclear magnetic resonance (2Hhyphen;NMR). Useful information about the cavity orientation and morphology, and internal surface area is obtained. Analysis of SEM photographs yields estimates of the surface area and the porosity of these membranes which complements the adsorption results. The orientation of liquid crystals permeated in the cavities of Anopore and Nuclepore membranes is probed with the2Hhyphen;NMR technique. It is found that the orientation of the liquid crystal molecules is governed by the confining volume and surface conditions. The2Hhyphen;NMR spectral line shape of the confined liquid crystal also provides information on the substrate morphology and roughness that is consistent with SEM and adsorption experiments.
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