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>Manyhyphen;body perturbation theory electronic structure calculations for the methoxy radical. II. Hyperfine coupling coefficients
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Manyhyphen;body perturbation theory electronic structure calculations for the methoxy radical. II. Hyperfine coupling coefficients
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机译：Manyhyphen;body perturbation theory electronic structure calculations for the methoxy radical. II. Hyperfine coupling coefficients
The methoxy radical undergoes the dynamic Jahnndash;Teller effect which gives rise to diagonal and offhyphen;diagonal hyperfine coupling constants. The offhyphen;diagonal constants are between the degenerate vibronic wave functions of the lowest spinndash;orbit level. The experimental hyperfine coupling constants were measured in terms of spherical tensors. In this paper the spherical tensors are expanded in Cartesian matrix elements. These expansions are used to calculate the hyperfine coupling constants, both the isotropic constants (also known as the Fermi contact terms) and the anisotropic constants (also known as the dipolar terms). The diagonal hyperfine coupling constants could be calculated by standard methods, but the offhyphen;diagonal hyperfine coupling constants had to be calculated between nonorthogonal orbitals. The calculated dipolar hyperfine terms, both diagonal and offhyphen;diagonal, are in fair agreement with the known experimental values. The calculated diagonal Fermi contact terms are in good agreement with experiment, while the calculated offhyphen;diagonal Fermi contact terms are in terrible agreement with experiment.
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