Infrared reflection spectroscopy for precise tracking of corrosion behavior in 3d-transition metals doped binary lead silicate glass

El-Batal FH; Khalil EMA; Hamdy YMZidan HMAziz MSAbdelghany AM

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Infrared reflection spectroscopy for precise tracking of corrosion behavior in 3d-transition metals doped binary lead silicate glass

机译：红外反射光谱法用于精确跟踪 3D 过渡金属掺杂二元硅酸铅玻璃的腐蚀行为

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Fourier transform infrared reflection (FTIRR) spectroscopy was used to monitor and confirm the proposed corrosion mechanisms and structural differences in the surface regions of some prepared undoped binary lead silicate PbO-SiO2 glass (LSG) together with samples doped with one of the first 3d-transition metal oxides (TMOs) (TiO2-->CuO) exposed to aqueous solutions of different pHs for a fixed time (1 h). The traditional proposed mechanism for silicate glass corrosion through ion exchange is analyzed to confirm and testify the applicability to such studied lead silicate glasses. The effects of 3d-transition metal oxides on the corrosion behavior of lead silicate glasses are followed and interpreted.

机译：采用傅里叶变换红外反射（FTIRR）光谱技术，对一些未掺杂的二元硅酸铅PbO-SiO2玻璃（LSG）以及掺杂首批3d过渡金属氧化物（TMO）（TiO2-->CuO）样品的表面区域的腐蚀机理和结构差异进行了监测和确认。分析了传统的硅酸盐玻璃离子交换腐蚀机理，以确认和证明对所研究的硅酸铅玻璃的适用性。跟踪并解释了3d过渡金属氧化物对硅酸铅玻璃腐蚀行为的影响。

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来源
《Physica, B. Condensed Matter》 |2010年第12期|2648-2653|共6页
作者
El-Batal FH; Khalil EMA; Hamdy YMZidan HMAziz MSAbdelghany AM;
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作者单位

Glass Research Department, National Research Centre, Dokki, Cairo, Egypt;

Spectroscopy Department, National Research Centre, Dokki, Cairo, Egypt;

Physics Deptartment, Faculty of Science Damitta, Mansoura University, Damitta, Egypt;

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正文语种英语
中图分类物理学;
关键词
Infrared reflectance spectroscopy; Lead silicate glass; Glass structure; Transition metals; Glass corrosion mechanism;

机译：红外反射光谱;硅酸铅玻璃;玻璃结构;过渡金属;玻璃腐蚀机理;

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Infrared reflection spectroscopy for precise tracking of corrosion behavior in 3d-transition metals doped binary lead silicate glass

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