Quantitative determination of longitudinal and transverse cross-relaxation rates

T. E. Malliavin; H. Desvaux; M. A. DelsucM. A. Delsuc

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Quantitative determination of longitudinal and transverse cross-relaxation rates

机译：定量测定纵向和横向交叉弛豫率

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We describe a quantitative processing method which give access to the longitudinal and transverse cross-relaxation rates from off-resonance ROESY intensities. This method takes profit of the dependence of the off-resonance ROESY experiments at any mixing time and any spin-lock angle #theta# on two relaxation matrices, the longitudinal and the transverse ones. This allows one to take into account multi-step magnetization transfers and to determine the longitudinal and transverse cross-off-resonance ROESY, relaxation, spin diffusion.

机译：我们描述了一种定量处理方法，该方法可以获得来自非共振ROESY强度的纵向和横向交叉弛豫速率。该方法利用了非共振ROESY实验在任何混合时间和任何自旋锁定角 #theta#对两个弛豫矩阵（纵向和横向）的依赖性。这允许人们考虑多步磁化转移，并确定纵向和横向交叉共振ROESY，弛豫，自旋扩散。

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《Journal de Chimie Physique et de Physico-Chimie Biologique》 |1999年第10期|1608-1615|共8页
作者
T. E. Malliavin; H. Desvaux; M. A. DelsucM. A. Delsuc;
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作者单位

Centre de Biochimie Structurale, INSERM U414, UMR C9955 du CNRS, Universite de Motpellier l, Faculte de Pharmacie, 15 avenue Ch. Flahault, 34060 Montpellier cedex 2, France;

Laboratoire de Biochimie Theorique, lBPC,11 rue Pierre et Matie Curie, 75005 Paris, France;

Laboratoire Commun de RMN, Service de Chimie Moleculaire, CEA Saclay, 91191 Gif-sur-Yvette cedex, FranceCentre de Biochimie Structurale, INSERM U414, UMR C9955 du CNRS, Universite de Montpellier l, Faculte de Pharmacie, 15 avenue Ch. Flahault, 34060 Montpellier cedex 2, France;

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正文语种英语
中图分类物理化学（理论化学）、化学物理学;
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Quantitative determination of longitudinal and transverse cross-relaxation rates

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