Synthesis and properties of the tetranuclear palladium chalcogenolato-acetato complex Pd(SePh)(OOCCH3)(4) with Pd-Pd bonding: an experimental and theoretical study

Nayek HP; Niedermeyer H; Dehnen S

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Synthesis and properties of the tetranuclear palladium chalcogenolato-acetato complex Pd(SePh)(OOCCH3)(4) with Pd-Pd bonding: an experimental and theoretical study

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The first tetranuclear palladium selenophenolate complex has been synthesized by reaction of palladium acetate with (PhSe)(3)Sn-(CH2)(4)-Sn(SePh)(3) (1) in dichloromethane. 1 represents a rectangular arrangement of the four Pd atoms bridged by four mu-bridging SePh and OAc groups each and is thermolyzed into a novel phase Pd10Se7. The alternating distribution of acetate or selenophenolate bridges over the Pd center dot center dot center dot Pd edges, that allows for the formation of two Pd-Pd bonds, was rationalized by quantum chemical investigations.

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第21期|4208-4212|共5页
作者
Nayek HP; Niedermeyer H; Dehnen S;
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作者单位

Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany.;

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原文格式 PDF
正文语种英语
中图分类化学;
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CRYSTAL-STRUCTURES; MOLECULAR PRECURSORS; BASIS-SETS; TRANSITION; REACTIVITY; THIOLATE; APPROXIMATION; SPECTROSCOPY; COORDINATION; CONVERSION;

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Synthesis and properties of the tetranuclear palladium chalcogenolato-acetato complex Pd(SePh)(OOCCH3)(4) with Pd-Pd bonding: an experimental and theoretical study

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