The bulk magnetization at temperatures of 1.8-400 K and in magnetic fields up to 70 kOe, the ambient temperature ~(13)C NMR spin-lattice relaxation, T_(1,C), and the elemental composition of three nanodiamond powder samples have been studied. The total magnetization of nanodiamond can be explained in terms of contributions from (1) the diamagnetic effect of carbon, (2) the paramagnetic effect of unpaired electrons present in nanodiamond grains, and (3) ferromagneticlike and (4) superparamagnetic contributions from Fecontaining particles detected in spatially resolved energy-dispersive spectroscopy. Contributions (1) and (2) are intrinsic to nanodiamond, while contributions (3) and (4) arise from impurities naturally present in detonation nanodiamond samples. ~(13)C NMR T_(1,C) relaxation would be unaffected by the presence of the ferromagnetic particles with the bulk magnetization of ～0.01 emu/g at 300 K. Thus, a reduction of T_(1,C) by 3 orders of magnitude compared to natural and synthetic microdiamonds confirms the presence of unpaired electrons in the nanodiamond grains. The spin concentration in nanodiamond powder corresponds to ～30 unpaired electrons per ～4.6 nm diameter nanodiamond grain.
展开▼
