Voltammetric behavior of TiO2 films on graphite electrodes prepared by liquid phase deposition

Zhang  JD; Yang  CZ; Gang  CZhu  HYOyama  M

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Voltammetric behavior of TiO2 films on graphite electrodes prepared by liquid phase deposition

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Electroactive TiO2 thin films were prepared on graphite electrodes from the aqueous solution of (NH4)(2)TiF6 and H3BO3 by the process of liquid phase deposition (LPD). By cyclic voltammetry, a cathodic peak assigned to the electroreduction of Ti(IV) species was exhibited in the voltammogram of LPD TiO2 film on graphite electrode in 0.2 M phosphate buffer solution (PBS) at pH 6.0. The dependence of the voltammetric behavior of LPD TiO2 electrode upon the pH value of PBS was observed. The effects of deposition time and concentrations of (NH4)(2)TiF6 and H3BO3 on the voltammetric response of TiO2 electrodes were described. (C) 2004 Elsevier B.V. All rights reserved.

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《Materials Chemistry and Physics》 |2004年第3期|398-403|共6页
作者
Zhang JD; Yang CZ; Gang CZhu HYOyama M;
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作者单位

Huazhong Univ Sci & Technol, Coll Environm Sci & Engn, Wuhan 430074, Peoples R China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类工程材料学;
关键词
TiO2 film; liquid phase deposition; cyclic voltammetry; OXIDE THIN-FILMS; NANOCRYSTALLINE TIO2; AQUEOUS-SOLUTION; PHOTOELECTROCHEMICAL CHARACTERIZATION; ELECTROCHEMICAL PROPERTIES; ANATASE; SPECTROSCOPY; ACCUMULATION; IMPEDANCE; POLYMER;

Voltammetric behavior of TiO2 films on graphite electrodes prepared by liquid phase deposition

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