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Describing the structure of a randomly hyperbranched polymer

机译:描述无规超支化聚合物的结构

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摘要

This paper describes random branching theory, a model for the solution structure of hyperbranched polymers. In this model, the hyperbranched polymer is assumed to be composed of units whose structure is simpler than the resulting polymer. These simple units can have any structure of chemical functionality, from monomers to linear chains or spherical particles. This paper outlines how this theory is constructed, describes the underlying assumptions and parameters, and summarizes the most basic form. It is shown how variations in the parameters change the behavior of the model, and described how to fit an experimental data series. This demonstrates how the model can be used to fit other data series, and how it can be used as a test for whether a polymer is randomly hyperbranched.
机译:本文介绍了随机支化理论,这是超支化聚合物溶液结构的模型。在该模型中,假定超支化聚合物由结构比所得聚合物简单的单元组成。这些简单的单元可以具有任何化学功能结构,从单体到线性链或球形颗粒。本文概述了该理论的构造方式,描述了基本假设和参数,并总结了最基本的形式。它显示了参数的变化如何改变模型的行为,并描述了如何拟合实验数据系列。这证明了该模型如何用于拟合其他数据序列,以及如何用作测试聚合物是否随机超支化的方法。

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