Complexation of (5H)-Dibenzolaa,dcyclohepten-5-ylidene to Palladium (II) via the Diazo Route and Evidence of C-H center dot center dot center dot Pd Interactions

Taubmann Christian; Oefele Karl; Herdtweck EberhardtHerrmann Wolfgang A.

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Complexation of (5H)-Dibenzolaa,dcyclohepten-5-ylidene to Palladium (II) via the Diazo Route and Evidence of C-H center dot center dot center dot Pd Interactions

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摘要

The reaction of 5-diazo-(5H)-dibenzo a,d cycloheptene with a palludium (II) precursor afforded the monomuclear carbocyclic carbene complex in high yield under mild conditions. Characterization of this complex using crystalographic and spectroscopic techniques unexpectedly revealed an almost planar carbocyclic ring system and rare intramolecular preagostic or anagostic C-H center dot center dot center dot Pd interactions.

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《Organometallics》 |2009年第15期|4254-4257|共4页
作者
Taubmann Christian; Oefele Karl; Herdtweck EberhardtHerrmann Wolfgang A.;
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作者单位

Tech Univ Munich, Dept Chem, Lehrstuhl Anorgan Chem, D-85747 Garching, Germany;

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原文格式 PDF
正文语种英语
中图分类 545B0014-1;
关键词
TRANSITION-METAL-COMPLEXES; CYCLOPROPENYLIDENE CARBENE LIGANDS; CARBOCYCLIC CARBENE; COUPLING REACTIONS; CARBENERHODIUM(I) COMPLEXES; DIAZOALKANE COMPLEXES; METHYLENE BRIDGE; CYCLOHEPTATRIENYLIDENE; CATALYSIS; CHEMISTRY;

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Complexation of (5H)-Dibenzolaa,dcyclohepten-5-ylidene to Palladium (II) via the Diazo Route and Evidence of C-H center dot center dot center dot Pd Interactions

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