Efficient Destruction of Pollutants in Water by a Dual-Reaction Center Fenton-like Process over Carbon Nitride Compounds-Complexed Cu(II)-CuAlO2

Lyu Lai; Yan Dengbiao; Yu GuangfeiCao WenruiHu Chun

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Efficient Destruction of Pollutants in Water by a Dual-Reaction Center Fenton-like Process over Carbon Nitride Compounds-Complexed Cu(II)-CuAlO2

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Carbon nitride compounds (CN) complexed with the in-situ-produced Cu(II) on the surface of CuAlO2 substrate (CN-Cu(II)-CuAlO2) is prepared via a surface growth process for the first time and exhibits exceptionally high activity and efficiency for the degradation of the refractory pollutants in water through a Fenton-like process in a wide pH range. The reaction rate for bisphenol A removal is similar to 25 times higher than that of the CuAlO2. According to the characterization, Cu(II) generation on the surface of CuAlO2 during the surface growth process results in the marked decrease of the surface oxygen vacancies and the formation of the C-O-Cu bridges between CN and Cu(II)-CuAlO2 in the catalyst. The electron paramagnetic resonance (EPR) analysis and density functional theory (DFT) calculations demonstrate that the dual reaction centers are produced around the Cu and C sites due to the cation-pi interactions through the C-O-Cu bridges in CN-Cu(II)-CuAlO2. During the Fenton-like reactions, the electron-rich center around Cu is responsible for the efficient reduction of H2O2 to (OH)-O-center dot, and the electron-poor center around C captures electrons from H2O2 or pollutants and diverts them to the electron-rich area via the C-O-Cu bridge. Thus, the catalyst exhibits excellent catalytic performance for the refractory pollutant degradation. This study can deepen our understanding on the enhanced Fenton reactivity for water purification through functionalizing with organic solid-phase ligands on the catalyst surface.

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《Environmental Science & Technology: ES&T》 |2018年第7期|4294-4304|共11页
作者
Lyu Lai; Yan Dengbiao; Yu GuangfeiCao WenruiHu Chun;
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作者单位

Tianjin Polytech Univ, Sch Environm & Chem Engn, Tianjin 300387, Peoples R China;

Chinese Acad Sci, Res Ctr Ecoenvironm Sci, Key Lab Drinking Water Sci & Technol, Beijing 100085, Peoples R China;

Guangzhou Univ, Sch Environm Sci & Engn, Res Inst Environm Studies Greater Bay, Minist Educ,Key Lab Water Qual & Conservat Pearl, Guangzhou 510006, Guangdong, Peoples R China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种英语
中图分类环境科学、安全科学;
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Efficient Destruction of Pollutants in Water by a Dual-Reaction Center Fenton-like Process over Carbon Nitride Compounds-Complexed Cu(II)-CuAlO2

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