Investigation on the thermal properties of Fe_2O(SO_4)_2 Part II

V. Petkova; Y. Pelovski

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Investigation on the thermal properties of Fe_2O(SO_4)_2 Part II

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Fe_2O(SO_4)_2 is a secondary product of the decomposition of FeSO_4·H_2O. Part I of this study presents results on the synthesis of Fe_2O(SO_4)_2 in gaseous environment containing either low or high concentration of oxygen. In this paper the existence of differences between the structures of Fe_2O(SO_4)_2 and Fe_2(SO_4)_3 is proved on the basis of a detailed thermal study of Fe_2O(SO_4)_2 upon dynamic heating (differential thermal analysis) and upon isothermal heating (thermal-analytic balance) in various gaseous environments as well as by presenting kinetic data on the processes of decomposition of both compounds.

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来源
《Journal of thermal analysis and calorimetry》 |2001年第3期|1037-1044|共8页
作者
V. Petkova; Y. Pelovski;
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作者单位

Central Laboratory of Mineralogy and Cristallography, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl. 107, 1113 Sofia, Bulgaria;

University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Str., 1756 Sofia, Bulgaria;

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正文语种英语
中图分类物理化学（理论化学）、化学物理学;
关键词
Fe_2O(SO_4)_2; Fe_2(SO_4)_3; kinetics; thermal decomposition;

Investigation on the thermal properties of Fe_2O(SO_4)_2 Part II

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