...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Polymer Science >Specific interchain interactions of poly(ethylene 2,5-furandicarboxylate) with polyglycolide acid blends and its effect on miscibility
【24h】

Specific interchain interactions of poly(ethylene 2,5-furandicarboxylate) with polyglycolide acid blends and its effect on miscibility

机译：

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Poly (ethylene 2,5-furan dicarboxylate) (PEF) with excellent physical properties is considered to be a perfect industrial alternative for PET. In this paper, a series of PEF/PGA blends with different mass ratios were prepared, and the miscibility and interchain-associated interactions of those blends were studied by differential scanning calorimetry, scanning electron microscopy, nuclear Magnetic Resonance Spectroscopy, FTIR spectroscopy, and wide-angle X-ray diffraction. Experiment results suggested that there are two specific interchain-associated interactions between PEF and PGA, which made those two components have good miscibility over the entire composition range and caused the T_gs of the blends slightly lower than the theoretical value calculated by FOX equation. After sufficiently isothermal crystallized at 160 ℃, the primary and secondary contribution of these two interchain-associated interactions between PEF and PGA in blends is reversed. In other words, the interchain-associated interactions composed of C O of PGA component and CH2 of PEF component is the primary role, the interchain-associated interactions composed of C O of PEF component and CH2 of PGA component is the secondary role before isothermal crystallization, after isothermal crystallization, which are reversed.

著录项

相似文献

  • 外文文献
  • 中文文献
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号