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Downshift of Raman peak in diamond powders

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Results are presented on the influence of the size of diamond powders and the laser power on the main Raman line. These results show conclusively that there is a consistent and systematic, reversible, downshift with both decrease of powder size, and increase of power. The shift can be explained by local heating of about 500 degrees C in the extreme case. Its significance applies to interpretation of the alleged;"downshifting" of the 1332 cm(-1) Line in all diamond research. In the future, the grain size, the thermal contact, and the beam power must be carefully monitored in reporting and interpreting any frequency shifts. References: 15

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