Crystal structures of the polymer precursors 3-(2,5-dimeth­oxy-3,4,6-tri­methyl­phen­yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo­cyclo­hexa-1,4-dien­yl)propyl methacrylate

Goswami S.K.; Hanton L.R.; McAdam C.J.Moratti S.C.Simpson J.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate

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Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate

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The closely related title compounds, 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate, C18H26O4 (I), and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate, C16H20O4 (II), are monomers suitable for the preparation of redox polymers. They consist of a propylmethacrylate group and three methyl substituents on dimethoxybenzene and quinone cores, respectively. Both crystal structures feature weak C—H⋯O hydrogen bonds and C—H⋯π(ring) contacts between methyl groups and the six-membered rings.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第5期|658-663|共6页
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Goswami S.K.; Hanton L.R.; McAdam C.J.Moratti S.C.Simpson J.;
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Crystal structures of the polymer precursors 3-(2,5-dimeth­oxy-3,4,6-tri­methyl­phen­yl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxo­cyclo­hexa-1,4-dien­yl)propyl methacrylate

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Crystal structures of the polymer precursors 3-(2,5-dimethoxy-3,4,6-trimethylphenyl)propyl methacrylate and 3-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)propyl methacrylate