Reaction of Iminopropadienones with Amines: Mechanistic Explanations of Zwitterionic Intermediate, Ketene and Ketenimine Formation

Rainer Koch; Justin J. Finnerty; Torsten Bruhn

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Reaction of Iminopropadienones with Amines: Mechanistic Explanations of Zwitterionic Intermediate, Ketene and Ketenimine Formation

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The complex reaction of thermally generated iminopropadienones with amines in the gas phase and upon matrix deposition and its varying product composition is investigated using density functional theory. In the high energy gas phase addition a single amine molecule reacts readily with iminopropadienone with the decisive step being a 1,3-hydrogen shift and activation barriers of at least 100 kJ/mol. In accordance with the experiment, the formation of ketenes is favored. In the condensed phase of an amine matrix, the utilization of amine dimers both as reagents and as explicit solvents lowers the activation energy required to a feasible 20-30 kJ/mol and predicts ketenimines as the main products, as observed experimentally.

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2008年第38期|8999-9004|共6页
作者
Rainer Koch; Justin J. Finnerty; Torsten Bruhn;
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Institut fiir Reine and Angewandte Chemie and Center of Interface Science, Carl von Ossietzky Universitdt Oldenburg, P.O. Box 2503, 26111 Oldenburg, Germany, Physique des Interactions Ionique et Moleculaire, UMR 6633, Universite de Provence et CNRS,;

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中图分类物理化学（理论化学）、化学物理学;
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Reaction of Iminopropadienones with Amines: Mechanistic Explanations of Zwitterionic Intermediate, Ketene and Ketenimine Formation

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