Catalytic oxidation of olefins with hydrogen peroxide catalyzed byFe(III)(salen)Clcomplex covalently linked to polyoxometalate

Valiollah Mirkhani; Majid Moghadam; Shahram Tangestaninejad

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Catalytic oxidation of olefins with hydrogen peroxide catalyzed byFe(III)(salen)Clcomplex covalently linked to polyoxometalate

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The catalytic activity of a hybrid compoundFe(salen)-POM(1)consisting of Fe(III)(salen)ClH2salen=N,N'-bis(salicylidene)eth-ylenediaminecomplex covalently linked to a Keggin type polyoxometalate,K8SiWnO39,(POM)was studied in the oxidation of various olefins in acetonitrile,using hydrogen peroxide as oxygen source.While,Fe(salen)-POMcatalyst showed moderate to good catalytic activity and product selectivity in the oxidation reactions,the complex Fe(III)(salen)Cl showed poor catalytic activity in these reactions.The effect of other parameters such solvent,oxidant,temperature and the metal type in Schiff base complex were also investigated.

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《Inorganic Chemistry Communications》 |2007年第12期|1537-1540|共4页
作者
Valiollah Mirkhani; Majid Moghadam; Shahram Tangestaninejad;
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作者单位

Chemistry Department,Catalysis Division,University of Isfahan,Isfahan 81746-73441,Iran;

Chemistry Department,Yasouj University,Yasouj 75914-353,Iran;

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原文格式 PDF
正文语种英语
中图分类无机化学;
关键词
Iron(III)-salen; Polyoxometalate; Oxidation; Hydrogen peroxide;

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机译：ChemInform Abstract: Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalyzed by Oxidatively‐ and Solvolytically‐Resistant Polyoxometalate Complexes.
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机译：ChemInform Abstract: Catalytic Oxidations with Hydrogen Peroxide as Oxidant. The Use of Polyoxometalates in Reactions with Hydrogen Peroxide
3. ChemInform Abstract: The Functionalization of Saturated Hydrocarbons. Part 21. The Fe(III)‐ Catalyzed and the Cu(II)‐Catalyzed Oxidation of Saturated Hydrocarbons by Hydrogen Peroxide: A Comparative Study. [J] . D. H. R. BARTON, S. D. BEVIERE, W. CHAVASIRIE. CSUHAID. DOLLER Chem Inform . 1992,第32期

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Catalytic oxidation of olefins with hydrogen peroxide catalyzed byFe(III)(salen)Clcomplex covalently linked to polyoxometalate

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