Crystal structure of catena-polybis­(N-acethyl­thio­morpholine-κS)copper(I)-μ-iodido

Chiang H.; Kim T.H.; Park H.Kim J.

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Crystal structure of catena-polybis(N-acethylthiomorpholine-κS)copper(I)-μ-iodido

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The reaction of copper(I) iodide with N-acetylthiomorpholine (L, C6H11NOS) in acetonitrile results in a coordination polymer with composition CuI(L)2n. The CuI atom is coordinated by two S atoms and two I atoms, adopting a distorted tetrahedral environment. The μ2-bridging mode of the I atoms gives rise to chains extending parallel to 010. C—H⋯O hydrogen-bonding interactions between the chains lead to a three-dimensional network.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第1期|53-55|共3页
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Chiang H.; Kim T.H.; Park H.Kim J.;
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Crystal structure of catena-polybis­(N-acethyl­thio­morpholine-κS)copper(I)-μ-iodido

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Crystal structure of catena-polybis(N-acethylthiomorpholine-κS)copper(I)-μ-iodido