Di-n-butyl#173;bis#173;N-(2-meth#173;oxy#173;eth#173;yl)-N-methyl#173;dithio#173;carbamato-#954;2S,S#8242;tin(IV): crystal structure and Hirshfeld surface analysis

Mohamad R.; Awang N.; Kamaludin N.F.Jotani M.M.Tiekink E.R.T.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Di-n-butyl#173;bis#173;N-(2-meth#173;oxy#173;eth#173;yl)-N-methyl#173;dithio#173;carbamato-#954;2S,S#8242;tin(IV): crystal structure and Hirshfeld surface analysis

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Di-n-butyl#173;bis#173;N-(2-meth#173;oxy#173;eth#173;yl)-N-methyl#173;dithio#173;carbamato-#954;2S,S#8242;tin(IV): crystal structure and Hirshfeld surface analysis

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摘要

The complete mol#173;ecule of the title compound, Sn(C4H9)2(C5H10NOS2)2, is generated by a crystallographic mirror plane, with the SnIV atom and the two inner methyl#173;ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di#173;thio#173;carbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C2S4 donor set defining a skew trapezoidal bipyramidal geometry; the n-butyl groups are disposed to lie over the longer Sn#8212;S bonds. Supra#173;molecular chains aligned along the a-axis direction and sustained by methyl#173;ene-C#8212;H#8943;S(weakly coordinating) inter#173;actions feature in the mol#173;ecular packing. A Hirshfeld surface analysis reveals the dominance of H#8943;H contacts in the crystal.

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来源
《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第2期|260-265|共6页
作者
Mohamad R.; Awang N.; Kamaludin N.F.Jotani M.M.Tiekink E.R.T.;
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作者单位

Biomedical Science Programme, School of Diagnostic and Applied Health Sciences, Faculty of Health Sciences, Universiti Kebangsaan Malaysia, Jalan Raja Muda Abdul Aziz, 50300 Kuala Lumpur, Malaysia;

Environmental Health and Industrial Safety Programme, School of Diagnostic and Applied Health Sciences, Faculty of Health Sciences, Universiti Kebangsaan Malaysia, Jalan Raja Muda Abdul Aziz, 50300 Kuala Lumpur, Malaysia;

Department of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad, Gujarat 380 001, IndiaResearch Centre for Chemical Crystallography, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia;

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正文语种英语
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关键词
CRYSTAL STRUCTURE; ORGANOTIN; DITHIOCARBAMATE; HIRSHFELD SURFACE ANALYSIS;

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Di-n-butyl#173;bis#173;N-(2-meth#173;oxy#173;eth#173;yl)-N-methyl#173;dithio#173;carbamato-#954;2S,S#8242;tin(IV): crystal structure and Hirshfeld surface analysis

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