Crystal structure of polytetra-#956;2-cyanido-1:2#954;8N:C-bis#173;(dimethyl sulfoxide-1#954;O)diargentate(I)iron(II)

Kucheriv O.I.; Naumova D.D.; Tokmenko I.I.Polunin R.A.Terebilenko K.V.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of polytetra-#956;2-cyanido-1:2#954;8N:C-bis#173;(dimethyl sulfoxide-1#954;O)diargentate(I)iron(II)

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Crystal structure of polytetra-#956;2-cyanido-1:2#954;8N:C-bis#173;(dimethyl sulfoxide-1#954;O)diargentate(I)iron(II)

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In the title polymeric complex, Fe{OS(CH3)2}2{Ag(CN)2}2, the FeII cation is located at an inversion centre and is coordinated by four cyanide (CN#8722;) anions and two dimethyl sulfoxide mol#173;ecules in a slightly compressed N4O2 octa#173;hedral geometry, the AgI cation is C-coordinated by two CN#8722; anions in a nearly linear geometry. The CN#8722; anions bridge the FeII and AgI cations to form a two-dimensional polymeric structure extending parallel to (102). In the crystal, the nearest Ag#8943;Ag distance between polymeric sheets is 3.8122#8197;(12)#8197;#197;. The crystal studied was a twin with a contribution of 0.2108#8197;(12) for the minor component.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第2期|270-272|共3页
作者
Kucheriv O.I.; Naumova D.D.; Tokmenko I.I.Polunin R.A.Terebilenko K.V.;
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作者单位

Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, Ukraine;

National O.O. Bogomoletz Medical University, 13 T. Shevchenko Blvd., Kyiv, Ukraine;

L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky 31, Kyiv 01601, Ukraine;

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正文语种英语
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CRYSTAL STRUCTURE; FEII COMPLEX; HOFMANN CLATHRATE ANALOGUE; DICYANIDOARGENTATE; METAL-ORGANIC FRAMEWORK;

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机译：四（6-甲基-2,2＆＃8242;-联吡啶）-1＆＃954; 2N，N＆＃8242 ;; 2＆＃954; 2N，N＆＃8242 ;; 3＆＃954; 2N，N＆＃8242 ;; 4＆＃954; 2N，N＆＃8242; -tetra-＆＃956; -nitrato-1：2＆＃954; 2O：O＆＃8242 ;; 2：3＆＃954; 3O：O＆＃8242 ;, O＆＃8242;＆＃8242 ;; 2：3＆＃954; 3O，O＆＃8242 ;: O＆＃8242;＆＃8242 ;; 3：4＆＃954; 2O：O＆＃8242; -tetranitrato-1＆＃954; 4O，O＆＃8242 ;; 4＆＃954; 2O，O＆＃8242; -tetralead（II）

Crystal structure of polytetra-#956;2-cyanido-1:2#954;8N:C-bis#173;(dimethyl sulfoxide-1#954;O)diargentate(I)iron(II)

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