Crystal structure of catena-polybis#173;(acetato-#954;O)copper(II)-bis#173;#956;-4-(1H-imidazol-1-yl)phenol-#954;2N3:O;#954;2O:N3

Poyraz M.; Sar#305; M.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of catena-polybis#173;(acetato-#954;O)copper(II)-bis#173;#956;-4-(1H-imidazol-1-yl)phenol-#954;2N3:O;#954;2O:N3

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Crystal structure of catena-polybis#173;(acetato-#954;O)copper(II)-bis#173;#956;-4-(1H-imidazol-1-yl)phenol-#954;2N3:O;#954;2O:N3

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In the title compound, Cu(CH3COO)2(C9H8N2O)2n, the CuII ion resides on a centre of inversion, displaying a tetra#173;gonally distorted octa#173;hedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1H-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1H-imidazol-1-yl)phenol ligands is associated with a very long Cu#8943;O inter#173;actions involving the phenol O atom of the heterocyclic ligand, which creates chains extending parallel to 100. In the crystal, the chains are arranged in a distorted hexa#173;gonal rod packing and are linked via C#8212;H#8943;O hydrogen bonds and by #960;#8211;#960; stacking inter#173;actions involving centrosymmetrically related pairs of imidazole and phenol rings.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第2期|209-212|共4页
作者
Poyraz M.; Sar#305; M.;
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作者单位

Department of Chemistry, Faculty of Science and Arts, Afyon Kocatepe University, TR-03200 Afyonkarahisar, Turkey;

Department of Physics Education, Gazi University, Beş

evler, TR-06500 Ankara, Turkey;

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正文语种英语
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CRYSTAL STRUCTURE; POLYMERIC STRUCTURE; HYDROGEN BONDS; COPPER(II); ACETATE; IMIDAZOLE; PI-PI STACKING;

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Crystal structure of catena-polybis#173;(acetato-#954;O)copper(II)-bis#173;#956;-4-(1H-imidazol-1-yl)phenol-#954;2N3:O;#954;2O:N3

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