Crystal structure of bis#173;(#956;-4-nitro#173;benzoato-#954;2O:O#8242;)bis#173;bis#173;(4-methyl#173;pyridine-#954;N)(4-nitro#173;benzoato-#954;2O,O#8242;)manganese(II)

Bharali S.J.; Bora S.J.; Das B.K.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of bis#173;(#956;-4-nitro#173;benzoato-#954;2O:O#8242;)bis#173;bis#173;(4-methyl#173;pyridine-#954;N)(4-nitro#173;benzoato-#954;2O,O#8242;)manganese(II)

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Crystal structure of bis#173;(#956;-4-nitro#173;benzoato-#954;2O:O#8242;)bis#173;bis#173;(4-methyl#173;pyridine-#954;N)(4-nitro#173;benzoato-#954;2O,O#8242;)manganese(II)

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The title compound, Mn2(C7H4NO4)4(C6H7N)4 or Mn2(#956;-NBz)2(#954;2-NBz)2(4-Mepy)4, where NBz is 4-nitro#173;benzoate and 4-Mepy is 4-methyl#173;pyridine, is a centrosymmetric dinuclear complex in which the MnII atoms are bridged by two NBz ligands with Mn#8943;Mn = 4.1324#8197;(4)#8197;#197;. The MnII atom in this dimeric species is present in a distorted octa#173;hedral environment with the four coordinating O atoms forming the equatorial plane and the two pyridyl N atoms occupying the axial sites. An important structural feature of the dimeric complex is that each of the bridging carboxyl#173;ate ligands binds to the metal ions in an asymmetric fashion involving bent and linear Mn#8212;O#8212;C units. The crystal packing is consolidated by C#8212;H#8943;O and C#8212;H#8943;#960; interactions.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2016年第11期|1549-1553|共5页
作者
Bharali S.J.; Bora S.J.; Das B.K.;
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作者单位

Department of Chemistry, Gauhati University, Guwahati 781 014, India;

Department of Chemistry, Pandu College, Guwahati 781 012, India;

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正文语种英语
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CRYSTAL STRUCTURE; MANGANESE 4-NITROBENZOATE; MNII TETRACARBOXYLATE DIMER; ASYMMETRIC CARBOXYLATE BRIDGE;

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机译：Tetra-＆＃956; -benzoato-＆＃954; 4O：O＆＃8242 ;;＆＃954; 3O：O，O＆＃8242 ;;＆＃954; 3O，O＆＃8242;：O＆＃8242; -bis [（benzoato-＆＃954; 2O，O＆＃8242;）（1,10-菲咯啉-＆＃954; 2N，N＆＃8242;）钕（III）]

Crystal structure of bis#173;(#956;-4-nitro#173;benzoato-#954;2O:O#8242;)bis#173;bis#173;(4-methyl#173;pyridine-#954;N)(4-nitro#173;benzoato-#954;2O,O#8242;)manganese(II)

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