Crystal structures of tetra#173;kis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)cobalt(II) monohydrate and bis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)zinc(II)

Neumann T.; Jess I.; Nther C.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structures of tetra#173;kis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)cobalt(II) monohydrate and bis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)zinc(II)

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Crystal structures of tetra#173;kis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)cobalt(II) monohydrate and bis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)zinc(II)

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Reaction of Co(NCS)2 and Zn(NCS)2 with 4-pyridine#173;thio#173;amide led to the formation of compounds with composition Co(NCS)2(C6H6N2S)4#183;H2O (1) and Zn(NCS)2(C6H6N2S)2 (2), respectively. The asymmetric unit of compound 1, consists of one cobalt(II) cation, two thio#173;cyanate anions, four 4-pyridine#173;thio#173;amide ligands and one water mol#173;ecule whereas that of compound 2 comprises one zinc(II) cation that is located on a twofold rotation axis as well as one thio#173;cyanate anion and one 4-pyridine#173;thio#173;amide ligand in general positions. In the structure of compound 1, the cobalt(II) cations are octa#173;hedrally coordinated by two terminal N-bonding thio#173;cyanate anions and by the N atoms of four 4-pyridine#173;thio#173;amide ligands, resulting in discrete and slightly distorted octa#173;hedral complexes. These complexes are linked into a three-dimensional network via inter#173;molecular N#8212;H#8943;S hydrogen bonding between the amino H atoms and the thio#173;cyanate S atoms. From this arrangement, channels are formed in which the water mol#173;ecules are embedded and linked to the host structure by inter#173;molecular O#8212;H#8943;S and N#8212;H#8943;O hydrogen bonding. In the structure of compound 2, the zinc(II) cations are tetra#173;hedrally coordinated by two N-bonding thio#173;cyanate anions and the N atoms of two 4-pyridine#173;thio#173;amide ligands into discrete complexes. These complexes are likewise connected into a three-dimensional network by inter#173;molecular N#8212;H#8943;S hydrogen bonding between the amino H atoms and the thio#173;amide S atoms.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2018年第2期|141-146|共6页
作者
Neumann T.; Jess I.; Nther C.;
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Institut fr Anorganische Chemie, Christian-Albrechts-Universitt Kiel, Max-Eyth Str. 2, D-24118 Kiel, Germany;

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CRYSTAL STRUCTURE; DISCRETE COMPLEX; COBALT(II) THIOCYANATE COMPLEX; ZINC(II) THIOCYANATE COMPLEX,4-PYRIDINETHIOAMIDE; HYDROGEN BONDING;

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1. ChemInform Abstract: Studies of Pendant Arm Macrocyclic Ligands. Part 7. Synthesis of Two Sexidentate Macrocycles Based Upon a Pyridine‐Containing Tetraaza Macrocycle with Either Two 2‐Pyridylmethyl or Two 1‐Pyrazolylmethyl Pendant Coordinating Arms, and Characterisation of Their Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes. Crystal Structure of ( 3,11‐Di(2‐pyridylmethyl)‐3,7,11,17‐tetraazabicyclo(11.3.1)heptadeca‐1( 17),13,15‐triene)nickel(II) Perchlorate. [J] . K. P. BALAKRISHNAN, H. A. A. OMAR, P. MOOREN. W. ALCOCKG. A. PIKE Chem Inform . 1991,第2期

机译：ChemInform Abstract: Studies of Pendant Arm Macrocyclic Ligands. Part 7. Synthesis of Two Sexidentate Macrocycles Based Upon a Pyridine‐Containing Tetraaza Macrocycle with Either Two 2‐Pyridylmethyl or Two 1‐Pyrazolylmethyl Pendant Coordinating Arms, and Characterisation of Their Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes. Crystal Structure of ( 3,11‐Di(2‐pyridylmethyl)‐3,7,11,17‐tetraazabicyclo(11.3.1)heptadeca‐1( 17),13,15‐triene)nickel(II) Perchlorate.
2. CRYSTAL STRUCTURE OF COORDINATION COBALT(II) AND ZINC(II) POLYMERS WITH 1,4-DIAZABICYCLO2.2.2OCTANE N,N '-DIOXIDE [J] . Abasheeva K. D., Demakov P. A., Dybtsev D. N.Fedin V. P. Journal of structural chemistry . 2022,第8期

机译：CRYSTAL STRUCTURE OF COORDINATION COBALT(II) AND ZINC(II) POLYMERS WITH 1,4-DIAZABICYCLO2.2.2OCTANE N,N '-DIOXIDE

Crystal structures of tetra#173;kis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)cobalt(II) monohydrate and bis#173;(pyridine-4-thio#173;amide-#954;N)bis#173;(thio#173;cyanato-#954;N)zinc(II)

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