N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ3N,O,O′di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis

Rosely S.N.B.M.; Hussen R.S.D.; Lee S.M.Halcovitch N.R.Jotani M.M.Tiekink E.R.T.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >N′-(4-Decyloxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ3N,O,O′dimethyltin(IV): crystal structure and Hirshfeld surface analysis

【24h】

N′-(4-Decyloxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ3N,O,O′dimethyltin(IV): crystal structure and Hirshfeld surface analysis

机译：

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The title diorganotin compound, Sn(CH3)2(C28H32N2O4), features a distorted SnC2NO2 coordination geometry almost intermediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an intramolecular hydroxy-O—H⋯N(hydrazinyl) hydrogen bond is noted. The alkoxy chain has an all-trans conformation, and to the first approximation, the molecule has local mirror symmetry relating the two Sn-bound methyl groups. Supramolecular layers sustained by imine-C—H⋯O(hydroxy), π–π between decyloxy-substituted benzene rings with an inter-centroid separation of 3.7724 (13) Å, C—H⋯π(arene) and C—H⋯π(chelate ring) interactions are formed in the crystal; layers stack along the c axis with no directional interactions between them. The presence of C—H⋯π(chelate ring) interactions in the crystal is clearly evident from an analysis of the calculated Hirshfeld surface.

著录项

来源
《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第3期|390-396|共7页
作者
Rosely S.N.B.M.; Hussen R.S.D.; Lee S.M.Halcovitch N.R.Jotani M.M.Tiekink E.R.T.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类
关键词

相似文献

外文文献
中文文献

1. Synthesis, Crystal Structures and Hirshfeld Surface Analysis of Bis-(di(2-methoxyphenyl)phosphoroselenoyl)-2,4-cyclopentadien-1-yl iron(II) and Ruthenium(II)eta(6)-arene Complex of Bis-(di(2-allylphenyl) phosphonite)-2,4-cyclopentadien-1-yliron (II) [J] . Mondal Dipanjan, Kunchur Harish S., Rao SowmyaMague Joel T.Balakrishna Maravanji S. Journal of chemical crystallography . 2022,第3期

机译：Synthesis, Crystal Structures and Hirshfeld Surface Analysis of Bis-(di(2-methoxyphenyl)phosphoroselenoyl)-2,4-cyclopentadien-1-yl iron(II) and Ruthenium(II)eta(6)-arene Complex of Bis-(di(2-allylphenyl) phosphonite)-2,4-cyclopentadien-1-yliron (II)
2. PLATINUM(II) COMPLEX CONTAINING N-(BIS(-2,4-DIMETHOXY-BENZYL)CARBAMOTHIOYL)-4-METHYLBENZAMIDE LIGAND: SYNTHESIS, CRYSTAL STRUCTURE, HIRSHFELD SURFACE ANALYSIS, AND ANTIMICROBIAL ACTIVITY [J] . U. Solmaz, E. Keskin, I. Gumus Журнал струκтурной химии . 2022,第1期

机译：PLATINUM(II) COMPLEX CONTAINING N-(BIS(-2,4-DIMETHOXY-BENZYL)CARBAMOTHIOYL)-4-METHYLBENZAMIDE LIGAND: SYNTHESIS, CRYSTAL STRUCTURE, HIRSHFELD SURFACE ANALYSIS, AND ANTIMICROBIAL ACTIVITY
3. PLATINUM(II) COMPLEX CONTAINING N-(BIS (-2,4-DIMETHOXY-BENZYL)CARBAMOTHIOYL)-4-METHYLBENZAMIDE LIGAND: SYNTHESIS, CRYSTAL STRUCTURE, HIRSHFELD SURFACE ANALYSIS, AND ANTIMICROBIAL ACTIVITY [J] . Solmaz U., Keskin E., Gumus ICevik P. K.Binzet G.Arslan H. Journal of structural chemistry . 2022,第1期

机译：PLATINUM(II) COMPLEX CONTAINING N-(BIS (-2,4-DIMETHOXY-BENZYL)CARBAMOTHIOYL)-4-METHYLBENZAMIDE LIGAND: SYNTHESIS, CRYSTAL STRUCTURE, HIRSHFELD SURFACE ANALYSIS, AND ANTIMICROBIAL ACTIVITY

N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ3N,O,O′di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis

摘要

著录项

相似文献

相关主题

期刊订阅

N′-(4-Decyloxy-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidato-κ3N,O,O′dimethyltin(IV): crystal structure and Hirshfeld surface analysis