Crystal structure of ({(1R,2R)-N,N#8242;-bis#173;(quino#173;lin-2-yl)methylcyclo#173;hexane-1,2-di#173;amine}#173;chlorido#173;iron(III))-#956;-oxido-tri#173;chlorido#173;ferrate(III) chloro#173;form monosolvate

Swift H.; Carrig M.W.; Oshin K.D.Vinokur A.I.Desper J.A.Levy C.J.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of ({(1R,2R)-N,N#8242;-bis#173;(quino#173;lin-2-yl)methylcyclo#173;hexane-1,2-di#173;amine}#173;chlorido#173;iron(III))-#956;-oxido-tri#173;chlorido#173;ferrate(III) chloro#173;form monosolvate

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Crystal structure of ({(1R,2R)-N,N#8242;-bis#173;(quino#173;lin-2-yl)methylcyclo#173;hexane-1,2-di#173;amine}#173;chlorido#173;iron(III))-#956;-oxido-tri#173;chlorido#173;ferrate(III) chloro#173;form monosolvate

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The first FeIII atom in the solvated title compound, Fe2Cl4O(C26H28N4)#183;CHCl3, adopts a distorted six-coordinate octa#173;hedral geometry. It is coordinated by one chloride ligand, four N atoms from the (1R,2R)-N,N#8242;-bis#173;(quinolin-2-yl)methylcyclo#173;hexane-1,2-di#173;amine ligand, and a bridging oxido ligand attached to the second FeIII atom, which is also bonded to three chloride ions. A very weak intra#173;molecular N#8212;H#8943;Cl hydrogen bond occurs. In the crystal, the coordination complexes stack in columns, and a grouping of six such columns create channels, which are populated by disordered chloro#173;form solvent mol#173;ecules. Although the Fe#8212;Cl bond lengths for the two metal atoms are comparable to the mean Fe#8212;Cl bond lengths as derived from the Cambridge Structural Database, the Fe#8212;O bond lengths are notably shorter. The solvent chloro#173;form mol#173;ecule exhibits `flip' disorder of the C#8212;H moiety in a 0.544#8197;(3):0.456#8197;(3) ratio. The only directional inter#173;action noted is a weak C#8212;H#8943;Cl hydrogen bond.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第7期|936-940|共5页
作者
Swift H.; Carrig M.W.; Oshin K.D.Vinokur A.I.Desper J.A.Levy C.J.;
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Department of Chemistry, Creighton University, Omaha, NE 68102, USA;

Department of Chemistry, University of Wisconsin, Madison, WI 53558, USA;

Department of Chemistry, Kansas State University, Manhattan, KS 66506, USA;

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CRYSTAL STRUCTURE; SIX-COORDINATE IRON(III) COMPLEX; BRIDGING OXIDO LIGAND; TETRADENTATE LIGAND; CHIRAL LIGAND;

Crystal structure of ({(1R,2R)-N,N#8242;-bis#173;(quino#173;lin-2-yl)methylcyclo#173;hexane-1,2-di#173;amine}#173;chlorido#173;iron(III))-#956;-oxido-tri#173;chlorido#173;ferrate(III) chloro#173;form monosolvate

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