KInAs2O7, a new diarsenate with the TlInAs2O7 structure type

Schwendtner K.; Kolitsch U.

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KInAs2O7, a new diarsenate with the TlInAs2O7 structure type

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Potassium indium diarsenate(V) was grown under mild hydrothermal conditions (T = 493 K, 7 d) at a pH value of about 1. It adopts the TlInAs2O7 structure type (P-1, Z = 4) and is closely related to the KAlP2O7 (P21/c) and RbAlAs2O7 (P-1) structure types. The framework topology of KInAs2O7 is built of two symmetrically non-equivalent As2O7 groups which share corners with InO6 octahedra. The K atoms are located in channels extending along 010.

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第9期|1294-1297|共4页
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Schwendtner K.; Kolitsch U.;
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机译：ChemInform Abstract: Dawson‐Type Heteropolyanions. Part 2. Synthesis of Lacunary Polyoxotungstoarsenate Derivatives of Octadecatungstodiarsenate. Study of the Structure of Octadeca(molybdotungstovanado)diarsenate Variants by 183W NMR.
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KInAs2O7, a new diarsenate with the TlInAs2O7 structure type

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